Synthesis and crystal structures of (C4H12N2)[Mn(HSeO3)2Cl2] и [(C4N12N2)Br]2[Mn(HSeO3)2Br2]: new representatives of the modular family of “layered hydroselenites”

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Single crystals of two new complex hydroselenites with organic cations, (C4H12N2)[Mn(HSeO3)2Cl2] (1) and [(C4N12N2)Br]2[Mn(HSeO3)2Br2] (2), were obtained as the products of the reaction of piperazine, selenious acid and manganese halide in an aqueous medium. The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis and are characterized by monoclinic symmetry (1: P21/c, a = 9.7557(7), b = 7.3930(5), c = 9.7660(6) Å, β = 116.839(7)°; 2: P21/c, a = 14.4093(3), b = 7.3822(1), c = 10.3051(3) Å, β = 101.553(2)°). The crystal structures of both compounds are constructed by alternating layers of the composition [Mn(HSeO3)2X2]2– (X = Cl, Br) and layers formed by piperazinium cations. Compound 1 is a structural analogue of the previously described compound (C4H12N2)[Cd(HSeO3)2Cl2], while the crystal structure of compound 2 belongs to a new structural type and contains layers including both piperazinium cations and bromine anions. The crystal structure of 2 is characterized by a modular structure.

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Sobre autores

V. Kireev

FRC Kola Science Centre RAS

Email: aks.crys@gmail.com
Rússia, 14 Fersman str., Apatity 184209

D. Dmitriev

FRC Kola Science Centre RAS; Lomonosov Moscow State University

Email: aks.crys@gmail.com

Faculty of Chemistry, Lomonosov Moscow State University

Rússia, 14 Fersman str., Apatity 184209; 1-3 Leninskie Gory, Moscow 119991

D. Charkin

FRC Kola Science Centre RAS; Lomonosov Moscow State University

Email: aks.crys@gmail.com

Faculty of Chemistry, Lomonosov Moscow State University

Rússia, 14 Fersman str., Apatity 184209; 1-3 Leninskie Gory, Moscow 119991

S. Aksenov

FRC Kola Science Centre RAS

Autor responsável pela correspondência
Email: aks.crys@gmail.com
Rússia, 14 Fersman str., Apatity 184209

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2. Fig. 1. General view of the crystal structure of (ppzH2)[Mn(HSeO3)2Cl2] (a), heteropolyhedral layer of [Mn(HSeO3)2Cl2] (b) and coordination environment of the piperazinium cation (c).

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3. Fig. 2. General view of the crystal structure of [(ppzH2)Br]2[Mn(HSeO3)2Br2] (a), features of the environment of ppzH22+ cations (MnO4Br2 octahedra) and characteristics of hydrogen bonds (b).

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4. Fig. 3. General view of the crystal structure of [(NH4)3(NO3)][Cu(HSeO3)2(NO3)2]. CuO6 octahedra and NH4 tetrahedra are shown.

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