Synthesis and optical properties of a heterocarboxylate complex with metalcore Zn2Eu

M. A. Uvarova; Уварова М. А.; I. V. Taidakov; Тайдаков И. В.; M. A. Shmelev; Шмелев М. А.; S. E. Nefedov; Нефедов С. Е.; I. L. Eremenko; Еременко И. Л.

doi:10.31857/S0132344X23700329

Synthesis and optical properties of a heterocarboxylate complex with metalcore Zn2Eu

Autores: Uvarova M.A.¹, Taidakov I.V.²^,3, Shmelev M.A.¹, Nefedov S.E.⁴, Eremenko I.L.¹
Afiliações:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
2. Lebedev Physics Institute, Russian Academy of Sciences, 119991, Moscow, Russia
3. Plekhanov Russian Economic University, 117997, Moscow, Russia
4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
Edição: Volume 49, Nº 12 (2023)
Páginas: 744-751
Seção: Articles
URL: https://rjonco.com/0132-344X/article/view/667633
DOI: https://doi.org/10.31857/S0132344X23700329
EDN: https://elibrary.ru/HQGFDW
ID: 667633

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Resumo

It has been shown that boiling aqueous europium(III) acetate with trifluoroacetic acid in a dioxane-acetonitrile mixture leads to the formation of a polymer {[Eu(μ-OOCCF3)3(OH2)2]}n (I) containing solvate dioxane molecules. The interaction of I in CH2Cl2 with [Phen2Zn2(µ-OOCBut)2(OOCBut)2] (II) at room temperature forms a precipitate, recrystallization of which from acetonitrile gives an unusual trinuclear heterometallic heteroanionic complex Phen2Zn2Eu(µ3-OH)(OOCBut)4(OOCCF3 )2 (III). The structure of the obtained compounds was established according to X-ray diffraction data (CCDC No. 2235937-2235939). The optical properties of complex III were studied.

Palavras-chave

trifluoroacetates, heterometallic complexes, europium, luminescence, phosphorescence, crystal structure

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