Электротранспортные свойства твердого раствора и композиционных образцов в системе Ba2In2O5–Ba2InNbO6 при изменении влажности атмосферы

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Аннотация

Изучены термические и электрические свойства твердого раствора и композиционных образцов в квазибинарной системе Ba2In2O5–Ba2InNbO6. Доказано, что во влажной атмосфере при температурах ниже 600°C образцы обратимо взаимодействуют с парами воды с образованием протонных дефектов. Процесс гидратации сопровождается значимым повышением общей электропроводности за счет появления вклада протонного переноса. Ниже температуры 500°C во влажном воздухе образцы являются преимущественно протонными проводниками. Установлен композиционный эффект протонной электропроводности.

Об авторах

Е.  С Матвеев

Уральский федеральный университет им. первого Президента России Б. Н. Ельцина

Email: Egor.Matveev@urfu.ru
Екатеринбург, Россия

Н.  А Кочетова

Уральский федеральный университет им. первого Президента России Б. Н. Ельцина

Екатеринбург, Россия

И.  В Алябышева

Уральский федеральный университет им. первого Президента России Б. Н. Ельцина

Екатеринбург, Россия

И.  Е Анимица

Уральский федеральный университет им. первого Президента России Б. Н. Ельцина

Екатеринбург, Россия

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