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Ammonia Decomposition Over Cobalt-Based Silica-Supported Fischer-Tropsch Synthesis Catalysts

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1. Title Title of document Ammonia Decomposition Over Cobalt-Based Silica-Supported Fischer-Tropsch Synthesis Catalysts
2. Creator Author's name, affiliation, country R. E. Yakovenko; Platov South-Russian State Polytechnic University (NPI)
2. Creator Author's name, affiliation, country T. V. Krasnyakova; Platov South-Russian State Polytechnic University (NPI); Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry
2. Creator Author's name, affiliation, country A. N. Saliev; Platov South-Russian State Polytechnic University (NPI)
2. Creator Author's name, affiliation, country M. A. Shilov; Platov South-Russian State Polytechnic University (NPI)
2. Creator Author's name, affiliation, country A. V. Volik; Platov South-Russian State Polytechnic University (NPI)
2. Creator Author's name, affiliation, country A. P. Savost’yanov; Platov South-Russian State Polytechnic University (NPI)
2. Creator Author's name, affiliation, country S. A. Mitchenko; Platov South-Russian State Polytechnic University (NPI); Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry
3. Subject Discipline(s)
3. Subject Keyword(s) ammonia decomposition; hydrogen production; cobalt-based silica-supported Fischer–Tropsch synthesis catalyst; promoter
4. Description Abstract

Decomposition of ammonia over silica-supported cobalt catalysts for Fischer–Tropsch synthesis has been studied at a pressure of 0.1 MPa, a gas hourly space velocity range of 1000–6000 h–1 and a temperature range of 400–650°C in a tubular fixed bed reactor in a flow-through mode. It was found that silica-supported cobalt catalysts for hydrocarbons synthesis via the Fischer–Tropsch protocol also exhibit high activity in ammonia decomposition. Both activity and hydrogen productivity decrease in the series: Co–Ru/SiO2 > > Co–Al2O3/SiO2 > Ru/SiO2 > Co–Al2O3/SiO2(35%)/ZSM-5(30%)/Al2O3(35%). The relatively low values of effective activation energies estimated for all catalysts indicate that the reaction can proceed with a high conversion at moderate temperatures.

5. Publisher Organizing agency, location The Russian Academy of Sciences
6. Contributor Sponsor(s)
7. Date (DD-MM-YYYY) 01.03.2023
8. Type Status & genre Peer-reviewed Article
8. Type Type
9. Format File format
10. Identifier Uniform Resource Identifier https://rjonco.com/0453-8811/article/view/660290
10. Identifier Digital Object Identifier (DOI) 10.31857/S0453881123020090
10. Identifier eLIBRARY Document Number (EDN) GNTPBZ
11. Source Title; vol., no. (year) Kinetika i kataliz; Vol 64, No 2 (2023)
12. Language English=en
13. Relation Supp. Files (340KB)
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14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
15. Rights Copyright and permissions Copyright (c) 2023 Р.Е. Яковенко, Т.В. Краснякова, А.Н. Салиев, М.А. Шилов, А.В. Волик, А.П. Савостьянов, С.А. Митченко