Synthesis of macrocyclic dithiadiperoxyspiroalkanes with the participation of lanthanide catalysts

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Abstract

An effective method has been developed for the synthesis of macrocyclic dithiadiperoxyspiroalkanes by cyclocondensation of alkane-α,ω-dithiols (butane-1,4-, pentane-1,5-, hexane-1,6-dithiols) with 1,1-dihydro-peroxycycloalkanes and formaldehyde with lanthanide catalysts.

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About the authors

N. N. Makhmudiyarova

Institute of Petrochemistry and Catalysis, Russian Academy of Sciences

Author for correspondence.
Email: natali-mnn@mail.ru
ORCID iD: 0000-0003-1952-4173
Russian Federation, prosp. Oktyabrya, 141, Ufa, 450075

I. R. Ishmukhametova

Institute of Petrochemistry and Catalysis, Russian Academy of Sciences

Email: natali-mnn@mail.ru
ORCID iD: 0000-0001-7964-5175
Russian Federation, prosp. Oktyabrya, 141, Ufa, 450075

U. M. Dzhemilev

Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: natali-mnn@mail.ru
Russian Federation, Leninsky prosp. 47, Moscow, 119991

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