Electron microscopy of ceramic materials based on thermal power plant fly ash

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅或者付费存取

详细

The importance of studying ceramic materials microstructure for controlling sintering processes which provide ceramic masses required performance characteristics is shown. The scanning electron microscopy (SEM) informativity in carrying out parametric structural analysis of building materials is noted. The physical principles that ensure electron microscopy high resolution and the various optical systems characteristics used in microscopic research methods are given. The samples prepared on modern equipment with application of a conductive layer on their surface were investigated, SEM and energy dispersive spectroscopy (EDS) were carried out using a KYKY EM 6900 electron microscope. Microstructure and features of pore space of the ceramic materials based on thermal power plant fly ash have been studied. A step-by-step procedure for setting up and conducting experiments is described, including study of the matrix structure at microscope resolution different limits, study of the matrix composite nuclei pore microstructure and the sample scanned surface elemental composition. The total elements concentration of EDS spectrum of the ceramic sample based on fly ash is presented. The SEM studies results are described indicating the peculiarities of the ceramic composite matrix structure formation that is a boundary layer forming a transition zone between the matrix and the core of the composite material. Features of the nuclei pore space fiber structure formation with fibers disorderly arrangement and abundance of air spaces between them.

全文:

受限制的访问

作者简介

A. Stolboushkin

Siberian State Industrial University

编辑信件的主要联系方式.
Email: stanyr@list.ru

Doctor of Sciences (Engineering)

俄罗斯联邦, 42, Kirova Street, Novokuznetsk, 654007

E. Isterin

Siberian State Industrial University

Email: eisterin@gmail.com

Engineer

俄罗斯联邦, 42, Kirova Street, Novokuznetsk, 654007

O. Fomina

Mechanical Engineering Research Institute of the Russian Academy of Sciences

Email: soa2@mail.ru

Candidate of Sciences (Engineering)

俄罗斯联邦, 4, Maly Kharitonyevsky Pereulok, Moscow, 101990

参考

  1. Patent RF No. 2835396. Syryevaya smes dlya izgotovleniya stenovykh keramicheskikh materialov i sposob ih polucheniya [The raw material mixture for the manufacture of ceramic wall materials and the method of their preparation]. Stolboushkin A.Yu., Isterin E.V., Fomina O.A. Declared 10.07.2024. Published 25.02.2025. (In Russian). EDN: NMYUME
  2. Mecholsky J.J. Evaluation of mechanical property testing methods for ceramic matrix composites. American Society-Bulletin. 1986. Vol. 65. No. 2, pp. 315–322.
  3. Abdrakhimova E.S., Abdrakhimov V.Z. On the use of aluminum-containing nanotechnogenic raw materials in the production of ceramic composite materials. Materialovedeniye. 2014. No. 12, pp. 44–52. (In Russian). EDN: TBSJBL
  4. Abdrakhimov V.Z., Abdrakhimova E.S. Ceramic wall materials based on fired sludge of alkaline etching of aluminum and intershale clay. Ekologiya Promyshlennogo Proizvodstva. 2015. No. 3 (91), pp. 8–11. (In Russian). EDN: UYCGQB
  5. Storozhenko G.I., Sebelev I.M., Simonov P.A. Production of wall (facade and effective) ceramics based on mechanically activated loess loams. Izvestiya of Higher Educational Institutions. Construction. 2023. No. 10 (778), pp. 21–34. (In Russian). EDN: CHIIFV. https://doi.org/10.32683/0536-1052-2023-778-10-21-34
  6. Guryeva V.A., Doroshin A.V., Dubineckij V.V. Ceramic bricks of semi-dry pressing with the use of fusible loams and non-traditional mineral raw materials. Solid State Phenomena. 2020. Vol. 299, pp. 252–257. EDN: UMPXJB. https://doi.org/10.4028/www.scientific.net/SSP.299.252
  7. Suvorova O.V., Selivanova E.A., Mikhailova J.A., Masloboev V.A., Makarov D.V. Ceramic products from mining and metallurgical waste. Applied Sciences (Switzerland). 2020. Vol. 10. No. 10. 3515. EDN: TGQQOY. https://doi.org/10.3390/app10103515
  8. Stolboushkin A.Yu., Berdov G.I., Vereshchagin V.I., Fomina O.A. Ceramic wall materials of matrix structure based on non-sintering low-plasticity technogenic and natural raw materials. Stroitel’nye Materialy [Construction Materials]. 2016. No. 8, pp. 19–23. (In Russian). EDN: WMSBOR
  9. Toturbiev B.D., Mamaev S.A., Toturbiev A.B. Low-fired, energy-saving, environmentally friendly technology for the production of ceramic materials based on clay shale. Geologiya i Geofizika Yuga Rossii. 2022. Vol. 12. No. 1, pp. 148–161. (In Russian). EDN: DSUZVE. https://doi.org/10.46698/VNC.2022.45.82.011
  10. Vlasov V.A., Skripnikova N.K., Semenovykh M.A., Volokitin O.G., Shekhovtsov V.V. Wall ceramic materials using technogenic iron-containing raw materials. Stroitel’nye Materialy [Construction Materials]. 2020. No. 8, pp. 33–37. (In Russian). EDN: LNTWYG. https://doi.org/10.31659/0585-430X-2020-783-8-33-37
  11. Ilyina L.V., Tatski L.N., Ulyanova O.V. Modification of low-quality clay raw materials with nanosilica gel and its effect on the properties of ceramic shards. Stroitel’stvo i rekonstruktsiya. 2022. No. 1 (99), pp. 120–133. (In Russian). EDN: UBPYZC. https://doi.org/10.33979/2073-7416-2022-99-1-120-133
  12. Kotlyar V.D., Kozlov A.V., Zhivotkov O.I., Kozlov G.A. Sand-lime brick based on ash microspheres and lime. Stroitel’nye Materialy [Construction Materials]. 2018. No. 9, pp. 17–21. (In Russian). EDN: XZJALZ. https://doi.org/10.31659/0585-430X-2018-763-9-17-21
  13. But T.S., Vinogradov B.N., Gavrilova T.I., Gorshkov V.S., Dolgopolov N.N., Myagkova M.A., Sirotkina N.L., Fadeeva V.S. Sovremennyye metody issledovaniya stroitel’nykh materialov [Modern methods of studying building materials]. Moscow: Gosstroyizdat.1962. 238 p.
  14. Manual of Symbols and Terminology. Pure and Applied Chemistry. 1972. Vol. 31. p. 577.
  15. Karnaukhov A.P. Adsorbtsiya. Tekstura dispersnykh i poristykh materialov [Adsorption. Texture of dispersed and porous materials]. Novosibirsk: Nauka. 1999. 470 p.
  16. Tekhnologicheskaya otsenka mineral’nogo syr’ya. Oprobovaniye mestorozhdeniy. Kharakteristika syr’ya: Spravochnik / Pod red. P.Ye. Ostapenko. [Technological assessment of mineral raw materials. Testing of deposits. Characteristics of raw materials: Handbook / Ed. P.E. Ostapenko]. Moscow: Nedra. 1990. 272 p.
  17. Yakovlev V.V., Kuzmin S.V., Gilmutdinov I.F., Nikitin O.N. Features of the application of scanning electron microscopy and electron probe X-ray spectral microanalysis methods in the study of radioactive materials. Collection of works of JSC “SSC RIAR”. Dimitrovgrad. 2023, pp. 3–11. (In Russian). EDN: FNERPC
  18. Stolboushkin A.Yu., Isterin E.V. Study of fly ash from the West Siberian Thermal Power Plant as a potential raw material for producing ceramics. Quality. Technologies. Innovations: Proceedings of the VI International Scientific and Practical Conference. Novosibirsk. 2023, pp. 96–103. (In Russian). EDN: PXPAPA
  19. Stolboushkin A.Yu., Isterin E.V., Fomina O.A. Use of thermal power engineering waste to reduce the average density of ceramic wall materials with a matrix structure. Stroitel’nye Materialy [Construction Materials]. 2024. No. 4, pp. 13–19. (In Russian). EDN: TPRBIP. https://doi.org/10.31659/0585-430X-2024-823-4-13-19

补充文件

附件文件
动作
1. JATS XML
下载
2. Fig. 1. Abrasive cutting machine METACUT-250: а – general view; b – double work table with T-shaped slots; 1 – diamond cutting disk; 2 – vice-type clamping device; 3 – liquid supply nozzles; 4 – metal guides; 5 – ceramic sample for SEM examination

下载 (724KB)
索引源数据
3. Fig. 2. Zenko Plasma tabletop carbon coating system: а – general view of the device; b – loading a ceramic sample into a vacuum chamber; c – pulsed heating of the chamber; d – 7-inch color touch screen with vacuum diagram, pulsed heating current and deposition of carbon fiber layers

下载 (470KB)
索引源数据
4. Fig. 3. Scanning electron microscope KYKY EM 6900: а – general view of the device; b – vacuum chamber; c – energy dispersive analyzer Oxford Xplore; d – loading the sample into the microscope; e – installing the ceramic sample on the working table: 1 – electron gun; 2 – sample positioning system; 3 – reflected electron detector; 4 – working table; 5 – sample with a dedicated area for observations

下载 (640KB)
索引源数据
5. Fig. 4. Image of the structure of a ceramic sample based on fly ash: а – zone B is a core covered with a shell; b – zone C is a shell (matrix) formed from the coating layer of the granule, and zone D is a core formed from an aggregated granule. Shooting conditions: SEM, 20 (а); 65 (b)

下载 (697KB)
索引源数据
6. Fig. 5. Image of the microstructure of a ceramic sample based on fly ash: (а, b, c) zone C is the matrix of the composite material; (d, e, f) zone D is the core of the composite material. Shooting conditions: SEM, 160 (а); 400 (b); 2000 (c); 80 (d); 400 (e); 1800 (f)

下载 (769KB)
索引源数据
7. Fig. 6. Image of the pore structure of the cores of a ceramic sample based on fly ash: 1 – pore; 2 – ash microsphere. Shooting conditions: SEM, 120 (а); 400 (b); 200 (c); 550 (d)

下载 (1MB)
索引源数据
8. Fig. 7. Energy dispersive microanalysis of a ceramic sample based on fly ash: а – electron image of the map; b – multilayer image of the EDS map; c – total spectrum of the EDS map

下载 (927KB)
索引源数据
9. Fig. 8. Layered color image of the EDS map of a ceramic sample based on fly ash for the main chemical elements: 1 – Fe; 2 – Ca; 3 – Si; 4 – Al; 5 – O; 6 – Mg

下载 (808KB)
索引源数据

版权所有 © ООО РИФ "СТРОЙМАТЕРИАЛЫ", 2025