Oxygen Storage Capacity of Y0.8Ca0.2BaCo4 – xMxO7 + δ (M = Fe, Ga, Al; 0 < x < 1) Solid Solutions during Thermal Cycling in Air

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Abstract

We have studied the behavior of Y1 – yCayBaCo4 – xMxO7 + δ solid solutions in cyclic oxygen absorption/release processes in air at temperatures in the range 350–580°C. Y0.8Ca0.2BaCoO7 + δ has been found to absorb the largest amount of oxygen: 0.52 wt % (325 μmol O/g). The incorporation of calcium and iron into the structure of the YBaCo4O7 + δ cobaltite has been shown to shift the oxygen exchange process to higher temperatures and increase the oxygen storage capacity of the material.

About the authors

D. I. Turkin

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: turkin@ihim.uran.ru
620108, Yekaterinburg, Russia

K. S. Tolstov

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: turkin@ihim.uran.ru
620108, Yekaterinburg, Russia

M. V. Yurchenko

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: turkin@ihim.uran.ru
620108, Yekaterinburg, Russia

A. Yu. Suntsov

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: turkin@ihim.uran.ru
620108, Yekaterinburg, Russia

V. L. Kozhevnikov

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Author for correspondence.
Email: turkin@ihim.uran.ru
620108, Yekaterinburg, Russia

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Copyright (c) 2023 Д.И. Туркин, К.С. Толстов, М.В. Юрченко, А.Ю. Сунцов, В.Л. Кожевников