Si3N4/TiN Ceramic Composites Produced by Hot Pressing

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Abstract

Si3N4/TiN ceramic composites have been prepared by hot pressing in a nitrogen atmosphere using fine Si3N4 and Ti powders and CaO–Al2O3 sintering aids and investigated. The results demonstrate that hot pressing was accompanied by titanium nitridation, yielding titanium nitride with the composition TiN0.9. Reaction between silicon nitride and the sintering aid led to the formation of a Ca-α-SiAlON with the composition Ca0.67(Si10Al2)(N15.3O0.7). In addition to the major phases, calcium aluminosilicate with the composition Ca3Al2Si3O12 was identified. Increasing the percentage of titanium nitride in the composites prepared at a temperature of 1650°C led to an increase in their density and Vickers microhardness: from 3.18 ± 0.03 to 4.33 ± 0.03 g/cm3 and from 17 ± 1.1 to 29.4 ± 0.9 GPa, respectively.

About the authors

K. A. Kim

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences

Email: frolovamarianna@bk.ru
119334, Moscow, Russia

A. S. Lysenkov

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences

Email: frolovamarianna@bk.ru
119334, Moscow, Russia

M. G. Frolova

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences

Email: frolovamarianna@bk.ru
119334, Moscow, Russia

Yu. F. Kargin

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119991, Moscow, Russia

Author for correspondence.
Email: ldenisova@sfu-kras.ru
Россия, 119991, Москва, Ленинский пр., 49

References

  1. Шевченко В.Я., Баринов С.М. Техническая керамика. M.: Наука, 1993. 187 с.
  2. Косолапова Т.Я., Андреева Т.В., Бартницкая Т.С., Гнесин Г.Г., Макаренко Г.Н., Осипова И.И., Прилуцкий Э.В. Неметаллические тугоплавкие соединения. М.: Металлургия, 1985. Т. 161.
  3. Андриевский Р.А. Нитрид кремния – синтез и свойства // Успехи химии. 1995. Т. 64. № 4. С. 311–329.
  4. Андриевский Р.А., Спивак И.И. Нитрид кремния и материалы на его основе. М.: Металлургия, 1984.
  5. Каргин Ю.Ф., Лысенков А.С., Ивичева С.Н., Закоржевский В.В., Боровинская И.П., Куцев С.В., Солнцев К.А. Керамика Si3N4 с модифицирующими добавками фаз системы CaO–Al2O3–AlN, полученная горячим прессованием // Неорган. материалы. 2012. Т. 48. № 11. С. 1291–1291.
  6. Журавлева Н.В., Лукин E.С. Керамика на основе нитрида кремния // Огнеупоры. 1993. С. 6–12.
  7. Zivkovic Lj., Nikolic Z., Boskovic S., Miljkovic M. Microstructural Characterization and Computer Simulation of Conductivity in Si3N4–TiN Composites // J. Alloys Compd. 2004. V. 373. № 1–2. P. 231–236. https://doi.org/10.1016/j.jallcom.2003.10.036
  8. Bellosi A., Guicciardi S., Tampieri A. Developmentand Characterization of Electroconductive Si3N4–TiN Composites // J. Eur. Ceram. Soc. 1992. V. 9. № 2. P. 83–93. https://doi.org/10.1016/0955-2219(92)90049-J
  9. Bracisiewicz M., Medri V., Bellosi A. Factors Inducing Degradation of Properties After Long Term Oxidation of Si3N4–TiN Electroconductive Composites // Appl. Surf. Sci. 2002. V. 202. № 3–4. P. 39–149. https://doi.org/10.1016/S0169-4332(02)00498-1
  10. Lee C.H., Lu H.H., Wang C.A., Nayak P.K., Huang J.L. Microstructure and Mechanical Properties of TiN/Si3N4 Nanocomposites by Spark Plasma Sintering (SPS) // J. Alloys Compd. 2010. V. 508. № 2. P. 540–545. https://doi.org/10.1016/j.jallcom.2010.08.116
  11. Lee B.T., Yoon Y.J., Lee K.H. Microstructural Characterization of Electroconductive Si3N4–TiN Composites // Mater. Lett. 2001. V. 47. № 1–2. P. 71–76. https://doi.org/10.1016/S0167-577X(00)00214-7
  12. Zou B., Huang C.Z., Liu H.L., Chen M. Preparation and Characterization of Si3N4/TiN Nanocomposites Ceramic Tool Materials // J. Mater. Process. Technol. 2009. V. 209. № 9. P. 4595–4600. https://doi.org/10.1016/j.jmatprotec.2008.10.025
  13. Zhou M., Zhong J., Zhao J., Rodrigo D., Cheng Y.B. Microstructures and Properties of Si3N4/TiN Composites Sintered by Hot Pressing and Spark Plasma Sintering // Mater. Res. Bull. 2013. V. 48. № 5. P. 1927–1933. https://doi.org/10.1016/j.materresbull.2013.01.045
  14. Guo Z., Blugan G., Kirchner R., Reece M., Graule T., Kuebler J. Microstructure and Electrical Properties of Si3N4–TiN Composites Sintered by Hot Pressing and Spark Plasma Sintering // Ceram. Int. 2007. V. 33. № 7. P. 1223–1229. https://doi.org/10.1016/j.ceramint.2006.03.029
  15. QiLiang H., Juan C., Wei P., Jian C., Jie L. In Situ Processing of TiN/Si3N4 Composites by Ti-Si3N4 Solid State Reaction // Mater. Lett. 1997. V. 31. № 3–6. P. 221–225. https://doi.org/10.1016/S0167-577X(96)00277-7
  16. Kiyono H., Miyake Y., Nihei Y., Tumura T., Shimada S. Fabrication of Si3N4-Based Composite Containing Needle-Like TiN Synthesized Using NH3 Nitridation of TiO2 Nanofiber // J. Eur. Ceram. Soc. 2012. V. 32. № 7. P. 1413–1417. https://doi.org/10.1016/j.jeurceramsoc.2011.04.008
  17. Лысенков А.С., Ким К.А., Каргин Ю.Ф., Фролова М.Г., Титов Д.Д., Ивичева С.Н., Перевислов С.Н. Композиты Si3N4–TiN, полученные горячим прессованием порошков нитрида кремния и титана // Неорган. материалы. 2020. Т. 56. № 3. С. 324–328. https://doi.org/10.31857/S0002337X20030112
  18. Каргин Ю.Ф., Ивичева С.Н., Лысенков А.С., Овсянников Н.А., Шворнева Л.И., Солнцев К.А. Композиты Si3N4/TiN, полученные из порошков Si3N4, модифицированных TiO2 // Неорган. материалы. 2012. Т. 48. № 9. С. 1017–1017.
  19. Gao L., Li J., Kusunose T., Niihara K. Preparation and Properties of TiN–Si3N4 Composites // J. Eur. Ceram. Soc. 2004. V. 24. № 2. P. 381–386. https://doi.org/10.1016/S0955-2219(03)00218-8
  20. Pezzotti G., Tanaka I., Ikuhara Y., Sakai M., Nishida T. Evidences for Dilute Solid Solutions in the Si3N4-TiN System // Scr. Metall. Mater. 1994. V. 31. № 4. P. 403–406.
  21. Jerebtsov D.A., Mikhailov G.G. Phase Diagram of CaO–Al2O3 System // Ceram. Int. 2001. V. 27. № 1. P. 25–28. https://doi.org/10.1016/S0272-8842(00)00037-7
  22. Wanbao H., Baolin Z., Hanrui Z., Wenlan L. Combustion Synthesis of Si3N4–TiN Composite Powders // Ceram. Int. 2004. V. 30. № 8. P. 2211–2214. https://doi.org/10.1016/j.ceramint.2004.01.005
  23. Mitomo M., Sato Y.I., Ayuzawa N., Yashima I. Plasma Etching of α-Sialon Ceramics // J. Am. Ceram. Soc. 1991. V. 74. № 4. P. 856–858. https://doi.org/10.1111/j.1151-2916.1991.tb06940.x
  24. Christensen A.N., Fregerslev S. Preparation, Composition, and Solid State Investigations of TiN, ZrN, NbN, and Compounds From the Pseudobinary Systems NbN–NbC, NbN–TiC, and NbN–TiN // Acta Chem. Scand. 1977. V. 31A. P. 861–868.
  25. Ким К.А., Лысенков А.С., Федоров С.В., Петракова Н.В., Фролова М.Г., Перевислов С.Н., Каргин Ю.Ф. Изучение влияния спекающей добавки CaO–Al2O3 (48 : 52 мас. %) на фазовый состав и свойства керамики на основе Si3N4 // Неорган. материалы. 2022. Т. 58. № 8. С. 908–916. https://doi.org/10.31857/S0002337X22080048

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Copyright (c) 2023 К.А. Ким, А.С. Лысенков, М.Г. Фролова, Ю.Ф. Каргин