Dielectric Properties of Copper(II) Oxide Nanoparticles Synthesized in a Vacuum Arc Discharge

I. V. Karpov; Карпов И. В.; A. V. Ushakov; Ушаков А. В.; L. Yu. Fedorov; Федоров Л. Ю.; E. A. Goncharova; Гончарова Е. А.; M. V. Brungardt; Брунгардт М. В.

doi:10.31857/S0002337X23070072

Dielectric Properties of Copper(II) Oxide Nanoparticles Synthesized in a Vacuum Arc Discharge

Authors: Karpov I.V.¹^,2, Ushakov A.V.¹^,2, Fedorov L.Y.¹^,2, Goncharova E.A.¹^,2, Brungardt M.V.¹^,2
Affiliations:
1. Siberian Federal University
2. Krasnoyarsk Scientific Center (Federal Research Center), Siberian Branch, Russian Academy of Sciences
Issue: Vol 59, No 7 (2023)
Pages: 788-795
Section: Articles
URL: https://rjonco.com/0002-337X/article/view/668219
DOI: https://doi.org/10.31857/S0002337X23070072
EDN: https://elibrary.ru/PTWIYW
ID: 668219

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Abstract
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Abstract

We have studied the effect of the size of copper oxide nanoparticles on their electrical transport properties. The nanoparticles have been synthesized by vacuum arc deposition and characterized by X-ray diffraction, X-ray photoelectron spectroscopy, and electron microscopy in order to determine their phase composition and size. The results demonstrate that raising the substrate temperature in the deposition process from 300 to 600 K increases the size of the forming nanoparticles from 5.4 to 37.7 nm. The frequency dependences of the electrical conductivity, dielectric permittivity, and dielectric loss tangent of the CuO nanoparticles in the range form 20 Hz to 1 MHz are influenced by their size. In the size range under consideration, distinctions in the dielectric properties of the nanoparticles can be understood in terms of the competing contributions of the competing contributions of the resistive and capacitive components for the particles and grain/particle boundaries.

Keywords

copper oxide, arc discharge, dielectric permittivity, electrical conductivity

References

Koteeswari P., Sagadevan S., Fatimah I., Sibhatu A.K., Abd Razak S.I., Leonard E., Soga T. Green Synthesis and Characterization of Copper Oxide Nanoparticles and Their Photocatalytic Activity // Inorg. Chem. Commun. 2022. V. 144. P. 109851. https://doi.org/10.1016/j.inoche.2022.109851
Angı A., Sanlı D., Erkey C., Birer Ö. Catalytic Activity of Copper(II) Oxide Prepared via Ultrasound Assisted Fenton-like Reaction // Ultrason. Sonochem. 2014. V. 21. № 2. P. 854–859. https://doi.org/10.1016/j.ultsonch.2013.09.006
Senthilkumar V., Kim Y.S., Chandrasekaran S., Rajagopalan B., Kim E.J., Chung J.S. Comparative Supercapacitance Performance of CuO Nanostructures for Energy Storage Device Applications // RSC Adv. 2015. V. 5. P. 20545–20553. https://doi.org/10.1039/C5RA00035A
Федоров Л.Ю., Ушаков А.В., Карпов И.В. Синтез и хеморезистивная чувствительность к водороду наноструктурированных пленок CuO // Письма в ЖТФ. 2022. Т. 48. № 14. С. 18–22. https://doi.org/10.21883/PJTF.2022.14.52864.19197
Lillo-Ramiro J., Guerrero-Villalba J.M., Mota-González M.L., Aguirre-Tostado F.S., Gutiérrez-Heredia G., Mejía-Silva I., Carrillo-Castillo A. Optical and Microstructural Characteristics of CuO Thin Films by Sol Gel Process and Introducing in Non-Enzymatic Glucose Biosensor Applications // Optik. 2021. V. 229. P. 166238. https://doi.org/10.1016/j.ijleo.2020.166238
Zhang Q., Zhang K., Xu D., Yang G., Huang H., Nie F., Liu C., Yang S. CuO Nanostructures: Synthesis, Characterization, Growth Mechanisms, Fundamental Properties, and Applications // Prog. Mater. Sci. 2014. V. 60. P. 208–337. https://doi.org/10.1016/j.pmatsci.2013.09.003
Zoolfakar A.S., Rani R.A., Morfa A.J., O’Mullaned A.P., Kalantar-Zadeh K. Nanostructured Copper Oxide Semiconductors: a Perspective on Materials, Synthesis Methods and Applications // J. Mater. Chem. C. 2014. V. 2. P. 5247–5270. https://doi.org/10.1039/C4TC00345D
El-Trass A., ElShamy H., El-Mehasseb I., El-Kemary M. CuO Nanoparticles: Synthesis, Characterization, Optical Properties and Interaction with Amino Acids // Appl. Surf. Sci. 2012. V. 258. P. 2997–3001. https://doi.org/10.1016/j.apsusc.2011.11.025
Rahmatolahzadeh R., Aliabadi M., Motevalli K. Cu and CuO Nanostructures: Facile Hydrothermal Synthesis, Characterization and Photocatalytic Activity Using New Starting Reagents // J. Mater. Sci. – Mater. Electron. 2017. V. 28. P. 148–156. https://doi.org/10.1007/s10854-016-5504-3
Сивков А.А., Назаренко О.Б., Ивашутенко А.С., Сайгаш А.С., Степанов К.И. Плазмодинамический синтез ультрадисперсных порошков на основе оксида меди // Изв. вузов. Физика. 2014. Т. 57. № 12–3. С. 309–314.
Гончарова Д.А., Лапин И.Н., Савельев Е.С., Светличный В.А. Структура и свойства наночастиц, полученных методом лазерной абляции объемных мишеней металлической меди в воде и этаноле // Изв. вузов. Физика. 2017. Т. 60. № 7. С. 98–106.
Oruç Ç., Altındal A. Structural and Dielectric Properties of CuO Nanoparticles // Ceram. Int. 2017. V. 43. № 14. P. 10708–10714. https://doi.org/10.1016/j.ceramint.2017.05.006
Makhlouf S.A., Kassem M.A., Abdel-Rahim M.A. Particle Size-Dependent Electrical Properties of Nanocrystalline NiO // J. Mater. Sci. 2009. V. 44. № 13. P. 3438–3444. https://doi.org/10.1007/s10853-009-3457-0
Карпов И.В., Ушаков А.В., Федоров Л.Ю., Гончарова Е.А., Брунгардт М.В. Исследование влияния размерных и поверхностных эффектов на электрофизические свойства наночастиц NiO, полученных в вакуумно-дуговом разряде // Неорган. материалы. 2022. Т. 58. № 10. С. 1079–1086. https://doi.org/10.31857/S0002337X22100074
Карпов И.В., Ушаков А.В., Лепешев А.А., Федоров Л.Ю. Плазмохимический реактор на основе импульсного дугового разряда низкого давления для синтеза нанопорошков // Журн. техн. физики. 2017. Т. 87. № 1. С. 140–145. https://doi.org/10.21883/JTF.2017.01.1851
Ушаков А.В., Карпов И.В., Федоров Л.Ю., Гончарова Е.А., Брунгардт М.В., Дёмин В.Г. Исследование влияния парциального давления кислорода на фазовый состав наночастиц оксида меди вакуумно-дугового синтеза // ЖТФ. 2021. Т. 91. № 12. С. 1986–1991. https://doi.org/10.21883/JTF.2021.12.51764.157-21
Кожанов А.Е., Никорич А.В., Рябова Л.И., Хохлов Д.Р. Проводимость твердых растворов Pb1–xSnxTe(In) в переменном электрическом поле // Физика и техника полупроводников. 2006. Т. 40. № 9. С. 1047–1050.
Deuermeier J., Gassmann J., Brotz J., Kleina A. Reactive Magnetron Sputtering of Cu2O: Dependence on Oxygen Pressure and Interface Formation with Indium Tin Oxide // J. Appl. Phys. 2011. V. 109. P. 113704. https://doi.org/10.1063/1.3592981
Chen J.W., Rao G.N. CuO Nanoparticles as a Room Temperature Dilute Magnetic Giant Dielectric Material // IEEE Trans. Magn. 2011. V. 47. № 10. P. 3772–3775. https://doi.org/10.1109/TMAG.2011.2149505
Psarras G.C. Hopping Conductivity in Polymer Matrix–Metal Particles Composites // Composites. Part A. 2006. V. 37. № 10. P. 1545–1553. https://doi.org/10.1016/j.compositesa.2005.11.004
Koshy J., Soosen S.M., Chandran A., George K.C. Correlated Barrier Hopping of CuO Nanoparticles // J. Semicond. 2015. V. 36. P. 122003. https://doi.org/10.1088/1674-4926/36/12/122003
Biju V., Abdul Khadar M. AC Conductivity of Nanostructured Nickel Oxide // J Mater. Sci. 2001. V. 36. P. 5779–5787. https://doi.org/10.1023/A:1012995703754