Extraction of Actinides and Lanthanides(III) from Nitric Acid Solutions with Mixtures of N-(Diphenylphosphoryl)-N'-propylureas with ω-Nitrogen-Containing Groups and Dinonylnaphthalenesulfonic Acid

A. N. Turanov; Туранов А. Н.; V. K. Karandashev; Карандашев В. К.; T. V. Baulina; Баулина Т. В.; E. I. Goryunov; Горюнов Е. И.; V. K. Brel; Брель В. К.

doi:10.31857/S0044457X22601900

Extraction of Actinides and Lanthanides(III) from Nitric Acid Solutions with Mixtures of N-(Diphenylphosphoryl)-N'-propylureas with ω-Nitrogen-Containing Groups and Dinonylnaphthalenesulfonic Acid

Authors: Turanov A.N.¹, Karandashev V.K.², Baulina T.V.³, Goryunov E.I.³, Brel V.K.³
Affiliations:
1. Osipyan Institute of Solid-State Physics, Russian Academy of Sciences
2. Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences
3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Issue: Vol 68, No 5 (2023)
Pages: 658-663
Section: ФИЗИКОХИМИЯ РАСТВОРОВ
URL: https://rjonco.com/0044-457X/article/view/665260
DOI: https://doi.org/10.31857/S0044457X22601900
EDN: https://elibrary.ru/SMRQXL
ID: 665260

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Abstract

Extraction of uranium, thorium, and lanthanide(III) ions from nitric acid solutions with mixtures of dinonylnaphthalenesulfonic acid and N-(diphenylphosphoryl)-N'-n-propylureas containing imidazolyl, diethylamino, pyrid-2-yl, and 2-oxopyrrolidine fragments has been studied in organic solvents. Considerable synergetic effect on extraction of metal ions with mixtures of dinonylnaphthalenesulfonic acid and N-(diphenylphosphoryl)-N'-[3-(2-oxopyrrolidino)propyl]urea has been revealed. Stoichiometry of extracted complexes has been determined. Effect of extractant strucuture, organic diluent nature, and HNO3 content in aqueous phase on extraction efficiency of metal cations into organic medium has been accessed.

Keywords

synergism, uranium(VI), thorium(IV), phosphine oxides

References

Myasoedov B.F., Kalmykov S.N., Kulyako Yu.M. et al. // Geochem. Int. 2016. V. 54. № 13. P. 1156. https://doi.org/10.1134/S0016702916130115
Аляпишев М.Ю., Бабаин В.А., Устынюк Ю.А. // Успехи химии. 2016. Т. 85. № 9. С. 943.
Leoncini A., Huskens J., Verboom W. // Chem. Soc. Rev. 2017. V. 46. № 23. P. 7229. https://doi.org/10.1039/C7CS00574A
Wilson A.M., Bailey P.J., Tasker P.A. et al. // Chem. Soc. Rev. 2014. V. 43. № 1. P. 123. https://doi.org/10.1039/C3CS60275C
Werner E.J., Biros S.M. // Org. Chem. Front. 2019. V. 6. № 12. P. 2067. https://doi.org/10.1039/c9qo00242a
Bhattacharyya A., Mohapatra P.K. // Radiochim. Acta. 2019. V. 107. № 9–11. P. 931. https://doi.org/10.1515/ract-2018-3064
Розен А.М., Крупнов Б.В. // Успехи химии. 1996. Т. 65. № 11. С. 1052
Myasoedov B.F., Chmutova M.K., Kochetkova N.E. et al. // Solv. Extr. Ion Exch. 1986. V. 4. № 1. P. 61. https://doi.org/10.1080/07366298608917853
Horwitz E.P., Martin K.A., Diamond H. et al. // Solv. Extr. Ion Exch. 1986. V. 4. № 3. P. 449. https://doi.org/10.1080/07366298608917877
Чмутова М.К., Литвина М.Н., Прибылова Г.А. и др. // Радиохимия. 1999. Т. 41. № 4. С. 331.
Тананаев И.Г., Летюшов А.А., Сафиуллина А.М. и др. // Докл. АН. 2008. Т. 422. № 6. С. 762.
Safiulina A.M., Goryunov E.I., Letyushov A.A. et al. // Mendeleev Commun. 2009. V. 19. P. 263. https://doi.org/10.1016/j.mencom.2009.09.010
Сафиулина А.М., Лизунов А.В., Семенов А.А. и др. // Аналитика. 2022. Т. 12. № 2. С. 114. https://doi.org/10.22184/2227-572X.2022.12.2.114.128
Сафиулина А.М., Лизунов А.В., Борисова Н.А. и др. // Журн. неорган. химии. 2021. Т. 66. № 5. С. 631.
Туранов А.Н., Карандашев В.К., Артюшин О.И. и др. // Журн. неорган. химии. 2020. Т. 65. № 8. С. 1099.
Danesi P.R., Chiarizia R., Scibona G. // J. Inorg. Nucl. Chem. 1973. V. 35. № 11. P. 3926. https://doi.org/10.1016/0022-1902(73)80089-2
Belova V.V., Martynova M.M., Tsareva Yu.V. et al. // J. Mol. Liq. 2019. V. 293. 111568. https://doi.org/10.1016/j.molliq.2019.111568
Белова В.В. // Радиохимия. 2021. Т. 63. № 1. С. 3.
Литвина М.Н., Чмутова М.К., Мясоедов Б.Ф. и др. // Радиохимия. 1996. Т. 38. № 6. С. 525.
Шадрин А.Ю., Бабаин В.А., Киселева Р.Н. // Радиохимия. 1993. Т. 35. № 1. С. 45.