Effect of Supersonic Nitrogen Flow on Ceramic Material Ta4HfC5–SiC

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Abstract

The behavior of the ceramic material Ta4HfC5-30 vol % SiC has been studied under the effect of supersonic flow of dissociated nitrogen, which is necessary to assess the potential application of these materials in oxygen-free gas environments at temperatures >1800°C. It has been found that as a result of heating the surface to ~2020°C in a few minutes there is a decrease to ~1915°C followed by a slow decrease to 188°C. This is probably due to the chemical processes occurring on the surface and the formation of an extremely rough microstructure. The ablation rate has been determined; it has been shown that neither at introduction of the sample into a high enthalpy nitrogen flow nor at sharp cooling (temperature drop to ~880°C in 9–10 s) cracking of the sample or detachment of the near-surface region has been observed. X-ray powder diffraction and Raman spectroscopy data allow us to conclude the complete removal of silicon carbide from the surface layer and the transformation of complex tantalum-hafnium carbide into the nitride.

About the authors

E. P. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Russian Federation, 119991, Moscow, Russia

N. P. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Russian Federation, 119991, Moscow, Russia

A. F. Kolesnikov

Ishlinskii Institute of Problems of Mechanics, Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Russian Federation, 119526, Moscow, Russia

A. V. Chaplygin

Ishlinskii Institute of Problems of Mechanics, Russian Academy of Sciences

Email: ep_simonenko@mail.ru
119526, Moscow, Russia

E. K. Papynov

Far Eastern Federal University

Email: ep_simonenko@mail.ru
690922, Vladivostok, Russia

O. O. Shichalin

Far Eastern Federal University

Email: ep_simonenko@mail.ru
690922, Vladivostok, Russia

A. A. Belov

Far Eastern Federal University

Email: ep_simonenko@mail.ru
690922, Vladivostok, Russia

I. A. Nagornov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: ep_simonenko@mail.ru
119526, Moscow, Russia

A. S. Mokrushin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: ep_simonenko@mail.ru
119991, Moscow, Russia

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: egorova.offver@gmail.com
119991, Moscow, Russia

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Copyright (c) 2023 Е.П. Симоненко, Н.П. Симоненко, А.Ф. Колесников, А.В. Чаплыгин, Е.К. Папынов, О.О. Шичалин, А.А. Белов, И.А. Нагорнов, А.С. Мокрушин, Н.Т. Кузнецов