Synthesis and Investigation of Na1 – xR0.33xTiO2(PO4)3 (R = Y or La) Phosphates

V. A. Sedov; Седов В. А.; Ya. B. Glyadelova; Гляделова Я. Б.; E. A. Asabina; Асабина Е. А.; V. I. Pet’kov; Петьков В. И.

doi:10.31857/S0044457X22601602

Synthesis and Investigation of Na1 – xR0.33xTiO2(PO4)3 (R = Y or La) Phosphates

Authors: Sedov V.A.¹, Glyadelova Y.B.¹, Asabina E.A.¹, Pet’kov V.I.¹
Affiliations:
1. Nizhny Novgorod State University
Issue: Vol 68, No 3 (2023)
Pages: 291-299
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjonco.com/0044-457X/article/view/665281
DOI: https://doi.org/10.31857/S0044457X22601602
EDN: https://elibrary.ru/JDQNEF
ID: 665281

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Abstract

Phosphates Na1 – xR0.33xTi2(PO4)3 (R = Y or La; 0 ≤ х ≤ 1) were synthesized by the Pechini process and characterized by X-ray diffraction, electron microscopy with microprobe analysis, and IR spectroscopy. The systems exhibit isodimorphism to form a series of solid solutions belonging to the NaZr2(PO4)3 (NZP) structural type and crystallizing in space group R
c or R
The Rietveld structural studies confirmed the isomorphic miscibility of sodium and the rare-earth element in the interstices of the NZP structure. The unit cell parameter с in the phosphates studied tends to increase, and the parameter а tends to decrease, in response to rising temperature, which trends are typical of NZP phosphates.

Keywords

NZP, phase formation, structure, thermal expansion, rare-earth elements

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