Features of Cadmium(II) Complexation with N-Donor Heterocyclic Ligands in the Presence of the Octadecahydroeicosaborate Anion

V. V. Avdeeva; Авдеева В. В.; A. S. Kubasov; Кубасов А. С.; S. E. Nikiforova; Никифорова С. Е.; L. V. Goeva; Гоева Л. В.; E. A. Malinina; Малинина Е. А.; N. T. Kuznetsov; Кузнецов Н. Т.

doi:10.31857/S0044457X23601165

Features of Cadmium(II) Complexation with N-Donor Heterocyclic Ligands in the Presence of the Octadecahydroeicosaborate Anion

Authors: Avdeeva V.V.¹, Kubasov A.S.¹, Nikiforova S.E.¹, Goeva L.V.¹, Malinina E.A.¹, Kuznetsov N.T.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 10 (2023)
Pages: 1413-1421
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://rjonco.com/0044-457X/article/view/666179
DOI: https://doi.org/10.31857/S0044457X23601165
EDN: https://elibrary.ru/YRVHUS
ID: 666179

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Abstract

The process of cadmium(II) complexation with 1-ethyl-2-(4-methoxyphenyl)azobenzimidazole (L1), 2,2′-bipyridyl (L2), and 1,10-phenanthroline (L3) in the presence of the [trans-B20H18]2– anion has been studied. It has been found that the nature of the organic ligand affects the composition and structures of the resulting compounds. Complexation with ligand L1, a benzimidazole derivative, has yielded binuclear complex [CdL12NO3(μ-NO3)CdL1(NO3)2] (1), which contains no boron cluster anion. In the case of azaheterocyclic ligands L2 and L3, depending on the Cd : L ratio, heteroleptic complexes [CdL2NO3]2[trans-B20H18] (L = L2 (2); L3 (3)) with coordinated nitrate ions (Cd : L = 1 : 2) or tris-chelate complexes [CdL3][trans-B20H18] (L = L2 (4); L3 (5)) with the boron cluster anion as a counterion (Cd : L = 1 : 3) have been isolated. The structures of complexes [CdL12NO3(μ-NO3)CdL1(NO3)2] (1) and [Cd(L2)2NO3]2[trans-B20H18] (2) have been determined by X-ray diffraction.

Keywords

cadmium(II), octadecahydroeicosaborate anion, azaheterocycles, benzimidazole derivatives

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