Characterization of New Pentanuclear Copper(II) and REE(III) Carboxylate Complexes

O. S. Pushikhina; Пушихина О. С.; E. V. Karpova; Карпова Е. В.; D. A. Tsarev; Царёв Д. А.; V. A. Tafeenko; Тафеенко В. А.; T. B. Shatalova; Шаталова Т. Б.

doi:10.31857/S0044457X23601189

Characterization of New Pentanuclear Copper(II) and REE(III) Carboxylate Complexes

Authors: Pushikhina O.S.¹, Karpova E.V.¹, Tsarev D.A.², Tafeenko V.A.¹, Shatalova T.B.¹
Affiliations:
1. Moscow State University
2. Mitoengineering Research Institute, Moscow State University
Issue: Vol 68, No 9 (2023)
Pages: 1324-1336
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://rjonco.com/0044-457X/article/view/666293
DOI: https://doi.org/10.31857/S0044457X23601189
EDN: https://elibrary.ru/WLVYXQ
ID: 666293

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Abstract

New pentanuclear complexes [Cu3M2(CHF2COO)12(H2O)8]·2H2O, where M = Er (I) and Nd (II), were synthesized by reacting individual copper haloacetates and REE in aqueous solution. The molecular structure of complex I was determined by single crystal X-ray diffraction analysis (CIF file CCDC no. 2159724). The structural features of the complexes and the nature of the carboxylate bridges between the metal centers affect the properties of these complexes; therefore, two similar compounds with the monochloroacetate ligand were prepared for comparison: [Cu3M2(СH2ClCOO)12(H2O)8]·2H2O, where M = Er (III) and Nd (IV). Compounds III and IV are isostructural to previously studied complexes of this type with other REE. Compounds I–IV were characterized by X-ray diffraction analysis and IR spectroscopy, and their thermal behavior was studied. To confirm the formation of precursors of molecular species of crystalline compound I, the solute species of the complexes were determined by electrospray ionization mass spectrometry (ESI-MS).

Keywords

heterometallic complex, complex species, haloacetate, crystal structure, thermal analysis

References

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