Di- and Octanuclear Iodoantimonates(III) with 1,2-Dimethylpyridinium and 3-Bromo-1-Ethyllpyridinium: Crystal Structure and Physico-Chemical Properties

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Abstract

By the reaction of SbI3 and iodides of the corresponding cations in organic solvents, two new antimony complexes were obtained — (3-Br-1-EtPy)3[Sb2I9] (1), (1,2-MePy)4[Sb8I28] (2). The features of the crystal structure of the compounds were determined by X-ray diffraction. The complexes are thermally stable up to at least 200°C and have a band gap of about 2.2 eV.

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About the authors

I. A. Shentseva

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: korobeynikov@niic.nsc.ru
Russian Federation, Novosibirsk

K. A. Tagiltsev

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Email: korobeynikov@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk

A. U. Usoltsev

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: korobeynikov@niic.nsc.ru
Russian Federation, Novosibirsk

N. A. Korobeynikov

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Author for correspondence.
Email: korobeynikov@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk

V. R. Shayapov

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: korobeynikov@niic.nsc.ru
Russian Federation, Novosibirsk

M. N. Sokolov

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: korobeynikov@niic.nsc.ru
Russian Federation, Novosibirsk

S. A. Adonin

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences; Irkutsk Favorsky Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: korobeynikov@niic.nsc.ru
Russian Federation, Novosibirsk; Irkutsk

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Supplementary files

Supplementary Files
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1. JATS XML
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2. Fig. 1. Non-covalent interactions (dotted line) in the crystal structure of compound 1. Hydrogen atoms are not shown

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3. Fig. 2. Structural type {α-M8I28} (a); anion structure of compound 2 (b). Antimony atoms are numbered

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4. Fig. 3. Contacts I···I (shown in dotted lines) in the anionic part of complex 2

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5. Fig. 4. Powder diffractograms of compounds 1 (a) and 2 (b): calculated from X-ray diffraction data (blue) and experimental (red)

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6. Fig. 5. TG, DTG, and DTA curves for junctions 1 (a) and 2 (b)

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7. Fig. 6. Diffuse reflection spectra of compounds 1 (a) and 2 (b)

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8. Supplementary 1
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9. Supplementary 2
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