Preparation of New Hybrid Materials SiO2@Melamine-Cyanurate as Precursors of Graphite-Like Carbon Nitride

М. D. Lebedev; Лебедев М. Д.; A. A. Goncharenko; Гончаренко А. А.; I. A. Skvortsov; Скворцов И. А.; M. S. Kuzmikov; Кузьмиков М. С.; A. S. Vashurin; Вашурин А. С.

doi:10.31857/S0044457X24040038

Preparation of New Hybrid Materials SiO2@Melamine-Cyanurate as Precursors of Graphite-Like Carbon Nitride

Authors: Lebedev М.D.¹, Goncharenko A.A.¹, Skvortsov I.A.¹, Kuzmikov M.S.¹^,2, Vashurin A.S.¹
Affiliations:
1. Ivanovo State University of Chemistry and Technology
2. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
Issue: Vol 69, No 4 (2024)
Pages: 480-487
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjonco.com/0044-457X/article/view/666557
DOI: https://doi.org/10.31857/S0044457X24040038
EDN: https://elibrary.ru/ZYWGJM
ID: 666557

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Abstract

This work describes the use of silica particles obtained by sol-gel method as a templat for deposition of supramolecular complexes of melamine cyanurate. To obtain SiO₂@melamine-cyanurate (SiO₂@MCA) material, the method of covalent modification of silica surface by melamine molecules (SiO₂-mel) was applied and the method of its further functionalization by hydrogen-bonded organic framework of melamine-cyanurate (HOF, MCA) was proposed. One of the promising directions of using SiO₂@melamine-cyanurate is obtaining SiO₂@g-C₃N₄ material on its basis. Control of the amount of applied melamine-cyanurate allows to potentially obtain g-C₃N₄ layers of different thicknesses on the silica surface.

Keywords

silica, nanoparticles, triazines

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References

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