Gas sensing properties of Ti0.2V1.8CTx/V2O5 nanocomposite

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Abstract

A method for the preparation of nanocomposite containing Ti0.2V1.8CTx MXene core and titanium-doped vanadium oxide surface layers as a result of relatively low-temperature partial oxidation of MXene multilayer - two-dimensional vanadium-titanium carbide has been developed. It is shown that during oxidation in air atmosphere of initial Ti0.2V1.8CTx at temperature 250°С, in general, the microstructure of accordion-like aggregates with some increase in porosity of their constituent layers and increase in their thickness due to the formation of V2O5 is preserved. At the same time, preservation of the MXene structure with a decrease in the interplanar spacing from 10.3 (initial powder Ti0.2V1.8CTx) to 7.3 Å was observed. Raman spectroscopy confirmed the formation of vanadium oxide. Kelvin-probe force microscopy data revealed that the formation of Ti0.2V1.8CTx/V2O5 nanocomposite results in a decrease in the work function from 4.88 (Ti0.2V1.8CTx) to 4.68 eV. The chemosensor properties towards a range of gaseous analytes (H2, CO, NH3, NO2, C6H6, C3H6O, CH4, C2H5OH and O2) have been comprehensively studied for Ti0.2V1.8CTx/V2O5 layers coated using the microplotter printing. At increased detection temperatures (125–200°С), high sensitivity to oxygen (10% O2) and NO2 (100 ppm) is observed; there are notable responses to humidity (50% RH) throughout the 25–200°С temperature range. At room temperature, good response to acetone, ethanol and ammonia is observed.

About the authors

E. P. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: ep_simonenko@mail.ru
Russian Federation, Moscow, 119991

A. S. Mokrushin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Russian Federation, Moscow, 119991

I. A. Nagornov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Russian Federation, Moscow, 119991

V. M. Sapronova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; D.I. Mendeleev Russian Chemical and Technological University

Email: ep_simonenko@mail.ru
Russian Federation, Moscow, 119991; Moscow, 125047

Yu. M. Gorban

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; D.I. Mendeleev Russian Chemical and Technological University

Email: ep_simonenko@mail.ru
Russian Federation, Moscow, 119991; Moscow, 125047

Ph. Y. Gorobtsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Russian Federation, Moscow, 119991

T. L. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Russian Federation, Moscow, 119991

N. P. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Russian Federation, Moscow, 119991

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Russian Federation, Moscow, 119991

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