Synthesis and Phase Formation in Ba0.9Ca0.1Zr0.05M0.10Ti0.85O3 (M = Mn, Fe, Co) Ceramics with Controllable Magnetic and Optical Properties

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Ceramic samples with perovskite structure of Ba0.9Ca0.1Zr0.05M0.10Ti0.85O3 (M = Mn, Fe, Co) were obtained by standard solid-phase synthesis methods. The processes of phase formation of samples by methods of X-ray phase analysis have been investigated, the parameters of unit cells have been determined. Magnetic and optical properties of the obtained samples were investigated by methods of magnetic susceptibility and diffuse reflection spectroscopy. It was found that the phase composition, as well as magnetic and optical properties depend on the nature of the introduced paramagnetic element.

Full Text

Restricted Access

About the authors

A. V. Fedorova

Institute of Silicate Chemistry of Russian Academy of Sciences

Author for correspondence.
Email: avfiodorova@gmail.com
ORCID iD: 0000-0001-8242-5608
Russian Federation, Saint Petersburg

A. A. Selyutin

Saint Petersburg State University

Email: avfiodorova@gmail.com
ORCID iD: 0000-0002-5467-5658
Russian Federation, Saint Petersburg

N. А. Medzatyi

Institute of Silicate Chemistry of Russian Academy of Sciences

Email: avfiodorova@gmail.com
Russian Federation, Saint Petersburg

References

  1. Žužić A., Ressle A., Macan J. // Ceram. Int. 2022. V. 48. № 19. P. 27240. https://doi.org/10.1016/j.ceramint.2022.06.152
  2. Папынов Е.К., Белов А.А., Шичалин О.О и др. // Журн. неорган. химии. 2021. Т. 66. № 5. С. 592. https://doi.org/10.31857/S0044457X21050135
  3. Goldschmidt V.M. // Naturwissenschaften. 1926. V. 14. № 21. P. 477. https://doi.org/10.1007/BF01507527
  4. Yang Y., Wang Y., Yang Z. et al. // J. Power Sources. 2019. V. 438. P. 22689. https://doi.org/10.1016/j.jpowsour.2019.226989
  5. Garg C., Roy D., Lonsky M. et al. // Phys. Rev. B. 2021. V. 103. https://doi.org/10.1103/PhysRevB.103.014437
  6. Chung S.Y., Kim I.D., Kang S.J. // Nat. Mat. 2004. V. 3. P. 774. https://doi.org/10.1038/nmat1238
  7. Hoang K. // Phys. Rev. Mat. 2017. V. 1. № 7. P. 075403. https://doi.org/10.1103/PhysRevMaterials.1.075403
  8. Никольская А.Б., Козлов С.С., Карягина О.К. и др. // Журн. неорган. химии. 2022. Т. 67. № 6. С. 862. https://doi.org10.31857/S0044457X22060174
  9. Jiang S., Hu T., Gild J. et al. // Scripta Mater. 2018. V. 142. P. 116. https://doi.org/10.1016/j.scriptamat.2017.08.040
  10. Biesuz M., Fu S., Dong J. et al. // J. Asian Ceram. Soc. 2019. V. 7. P. 127. https://doi.org/10.1080/21870764.2019.1595931
  11. Witte R., Sarkar A., Kruk R. et al. // Phys. Rev. Mat. 2019. V. 3. P. 034406. https://doi.org/10.1103/PhysRevMaterials.3.034406
  12. Mao A., Xiang H., Zhang Z. et al. // J. Magn. Magn. Mater. 2020. V. 497. № 1. P. 165884. https://doi.org/10.1016/j.jmmm.2019.165884
  13. Бобрышева Н.П., Селютин А.А., Козин А.О. // Журн. общ. химии. 2014. Т. 84. № 3. С. 355.
  14. Ren K., Wang Q., Shao G. et al. // Scripta Mater. 2020. V. 178. P. 382. https://doi.org/10.1016/j.scriptamat.2019.12.006
  15. Zhao Z., Xiang H., Dai F-Z. et al. // J. Mater. Sci. Technol. 2019. V. 35. № 11. P. 2647. https://doi.org/10.1016/j.jmst.2019.05.054
  16. Zhang K., Li W., Zeng J. et al. // J. Alloys Compd. 2020. V. 817. https://doi.org/10.1016/j.jallcom.2019.153328
  17. Jiang S., Hu T., Gild J. et al. // Scripta Mater. 2018. V. 142. № 1. P. 116. https://doi.org/10.1016/j.scriptamat.2017.08.040
  18. Sarkar A., Djenadic R., Wang D. et al. // J. Eur. Ceram. Soc. 2018. V. 38. P. 2318. https://doi.org/10.1016/j.jeurceramsoc.2017.12.058
  19. Biesuz M., Fu S., Dong J. et al. // J. Asian Ceram. Soc. 2019. V. 7. P. 127. https://doi.org/10.1080/21870764.2019.1595931
  20. Sharma Y., Musico B.L., Gao X. et al. // Phys. Rev. Mater. 2018. V. 2. P. 060404. https://doi.org/10.1103/PhysRevMaterials.2.060404
  21. Zhong Y., Sabarou H., Yan X. et al. // Mater. Des. 2019. V. 182. P. 108060. https://doi.org/10.1016/j.matdes.2019.108060
  22. Гельчинский Б.Р., Балякин И.А., Юрьев А.А. и др. // Успехи химии. 2022. Т. 91. № 6. P. RCR5023. https://doi.org/10.1070/RCR5023
  23. Oses C., Toher C., Curtarolo S. // Nat. Rev. Mater. 2020 V. 5. P. 295. https://doi.org/10.1038/s41578-019-0170-8
  24. Venkatesh G., Blessto В., Santhosh K.R. et al. // IOP Conf. Ser. Mater. Sci. Eng. 2018. V. 314. Art. 653. https://doi.org/10.1088/1757-899X/314/1/012010
  25. Toher C., Oses C., Esters M. et al. // MRS Bull. 2022. V. 47. P. 194. https://doi.org/10.1557/s43577-022-00281-x
  26. Hao J., Bai W., Li W., Zhai J. // J. Am. Ceram. Soc. 2012. V. 95. № 6. P. 1998. https://doi.org/10.1111/j.1551-2916.2012.05146.x
  27. Mezzourh H., Belkhadir S., Mezzane D. et al. // Phys. B. 2021. V. 603. P. 412760. https://doi.org/10.1016/j.physb.2020.412760
  28. Shankar J., KumarA.S., Sudheer Kumar R.V. // Ferroelectrics. 2023. V. 606. № 1. P. 207. https://doi.org/10.1080/00150193.2023.2189837
  29. Селютин А.А., Ширкин А.Ю., Касаткин И.А. и др. // Журн. общ. химии. 2015. Т. 85. № 3. С. 506.
  30. Rani A., Kolte J. Gopalan P. // Appl. Phys. A. 2022. V. 128. P. 442. https://doi.org/10.1007/s00339-022-05523-y
  31. Liu R., Chen Z., Lu Z. et al. // Ceram. Int. 2022. V. 48. № 2. P. 2377. https://doi.org/10.1016/j.ceramint.2021.10.018
  32. Chakraborty A., Liton M.N.H., Sarker M.S.I. et al. // Physica B: Condens. Matter. 2023. V. 648. https://doi.org/10.1016/j.physb.2022.414418
  33. Shangguan M., Zhang X., Wang C. et al. // J. Eur. Ceram. Soc. 2023. V. 43. № 15. P. 6883. https://doi.org/10.1016/j.jeurceramsoc.2023.06.038
  34. Derkaoui I., Achehboune M., Boukhoubza I. et al. // Comput. Mater. Sci. 2023. V. 217. P. 111913. https://doi.org/10.1016/j.commatsci.2022.111913
  35. Meng Y., Liu K., Zhang X. et al. // J. Am. Ceram. Soc. 2022. V. 105. № 9. P. 5725. https://doi.org/10.1111/jace.18512
  36. Sherlin Vinita V., Sahaya Jude Dhas S., Suresh S. et al. // J. Magn. Magn. Mater. 2023. V. 565. https://doi.org/10.1016/j.jmmm.2022.170251
  37. Wang S., Zhu T., Sabatini R. et al. // Adv. Mater. 2022. V. 34. https://doi.org/10.1002/adma.202207261
  38. Shannon R.D., Prewitt C.T. // Acta Crystallogr., Sect. B. 1969. V. 25. P. 925. https://doi.org10.1107/S0567740869003220
  39. Калинников В.Т., Ракитин Ю.В. Введение в магнетохимию. Метод статической магнитной восприимчивости в химии. М.: Наука, 1980. 302 c.
  40. Ракитин Ю.В., Калинников В.Т. Современная магнетохимия. СПб.: Наука, 1994. 276 с.
  41. Федорова А.В., Чежина Н.В. // Журн. общ. химии. 2019. Т. 89. № 6. С. 917. https://doi.org10.1134/S0044460X19060099
  42. Федорова А.В., Чежина Н.В., Пономарева Е.А. и др. // Журн. общ. химии. 2023. Т. 93. № 1. С. 135. https://doi.org10.31857/S0044460X23010158

Supplementary files

Supplementary Files
Action
1. JATS XML
Download
2. Fig. 1. Diffractograms of Ba0.9Ca0.1Zr0.05Mn0.10Ti0.85O3 samples obtained by the standard solid-phase method under different charge calcination conditions.

Download (86KB)
Indexing metadata
3. Fig. 2. Diffractograms of Ba0.9Ca0.1Zr0.05Fe0.10Ti0.85O3 samples obtained by the standard solid-phase method under different charge calcination conditions.

Download (91KB)
Indexing metadata
4. Fig. 3. Diffractograms of Ba0.9Ca0.1Zr0.05Co0.10Ti0.85O3 samples obtained by the standard solid-phase method under different charge calcination conditions.

Download (86KB)
Indexing metadata
5. Fig. 4. Temperature dependence of the experimental values of the effective magnetic moment (µef) for Ba0.9Ca0.1Zr0.05Fe0.10Ti0.85O3 (1), Ba0.9Ca0.1Zr0.05Mn0.10Ti0.85O3 (2), Ba0.9Ca0.1Zr0.05Co0.10Ti0.85O3 (3) samples.

Download (62KB)
Indexing metadata
6. Fig. 5. Diffuse absorption spectra of Ba0.9Ca0.1Zr0.05Fe0.10Ti0.85O3 (1), Ba0.9Ca0.1Zr0.05Mn0.10Ti0.85O3 (2), Ba0.9Ca0.1Zr0.05Co0.10Ti0.85O3 (3) samples.

Download (98KB)
Indexing metadata
7. Fig. 6. Diffuse reflectance spectra of samples: a - Ba0.9Ca0.1Zr0.05Fe0.10Ti0.85O3 (a); b - Ba0.9Ca0.1Zr0.05Mn0.10Ti0.85O3 (b); c - Ba0.9Ca0.1Zr0.05Co0.10Ti0.85O3 (c). E, eV.

Download (120KB)
Indexing metadata

Copyright (c) 2024 Russian Academy of Sciences