The Iminoacylation Reaction of Iodoaniline with [2-B10H9NCCH3]– Anion is a Route to the Preparation of New Boron-Containing Synthons

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Abstract

This work is devoted to the study of the nucleophilic addition reaction of isomers of iodo-aniline to the nitrile derivative of closo-decaborate anion. The structure of the products was established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu4)[2-B10H9NHC(CH3)HN(2-C6H4I)] was established by single crystal X-ray analysis.

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About the authors

A. P. Zhdanov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

A. V. Nelyubin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

N. A. Selivanov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

A. Yu. Bykov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

A. S. Kubasov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

I. N. Klyukin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

K. Yu. Zhizhin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

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Supplementary files

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2. Fig. 1. General scheme of the reaction.

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3. Fig. 2. Fragment of 1H NMR spectra of compounds 2 (a), 3 (b), 4 (c).

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4. Fig. 3. Structure of the anion [2-B10H9NH=C(CH3)NH(2-C6H4I)]- based on single crystal PCA data.

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5. Fig. 4. Supramolecular interactions in structure 2.

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