New Method for the Synthesis of Acetylacetone-Based Closo-Borate Anion Derivatives [BnHn–1NH=C(R)C(C(OH)CH3)C(O)CH3]–, Where n = 10, 12, R = Me, Et

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Abstract

The processes of nucleophilic addition of acetylacetone as a C-nucleophile to multiple bonds of nitrile derivatives of boron cluster anions have been studied in this work. The structure of the products was established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu4)[2-B10H9NH=C(C2H5)C(C(OH)CH3)C(O)CH3] was established by single crystal X-ray analysis.

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About the authors

A. V. Nelyubin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

N. A. Selivanov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

A. Yu. Bykov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

A. S. Kubasov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

I. N. Klyukin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

A. P. Zhdanov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

K. Yu. Zhizhin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

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Supplementary files

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2. Fig. 1. Scheme of the reaction of nucleophilic addition of acetylacetone to [B12H11NCR]anions (R = Me, Et).

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3. Fig. 2. Scheme of the nucleophilic addition reaction of acetylacetone to [2-B10H9NCR]anions (R = Me, Et).

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4. Fig. 3. Structure of the anion [2-B10H9NH=C(C2H5)C(C(OH)CH3)C(O)CH3]- according to single crystal PCA data.

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5. Fig. 4. Hydrogen bonds in the acetylacetonate moiety.

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