Optimisation of nickel ferrite production conditions for the preparation of magnetic composite photocatalysts

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

Ferrites of non-ferrous metals are promising magnetic catalysts that can be easily separated from the reaction mixture after use by applying a magnetic field. However, these materials have a fast electron-hole relaxation time, which reduces their activity in photoreactions. This problem is overcome by creating hybrid nanostructures based on ferrites, for example with zinc oxides. The catalytic activity of such structures depends highly on the method of their synthesis. In this work, the alkaline co-precipitation of Fe2+ and Ni2+ ions, which have similar values for hydroxides, was used to obtain stoichiometric and homogeneous nickel ferrite precursors. The influence of the reaction parameters on the purity of the nickel ferrite phase and the size of the particles was studied using the experimental design technique. Spherical nanoparticles 15.9 ± 1.1 nm in diameter were produced under the optimal conditions identified. Based on the obtained material, NiFe2O4/ZnO magnetic composites of different quantitative compositions were prepared. The photocatalytic activity of the hybrid structures was demonstrated by photodegradation of crystal violet dye.

Texto integral

Acesso é fechado

Sobre autores

D. Nemkova

Siberian Federal University

Autor responsável pela correspondência
Email: diana.saykova@mail.ru
Rússia, Krasnoyarsk, 660041

S. Saikova

Siberian Federal University; Institute of Chemistry and Chemical Engineering, Krasnoyarsk Scientific Center (Federal Research Center), Siberian Branch, Russian Academy of Sciences

Email: diana.saykova@mail.ru
Rússia, Krasnoyarsk, 660041; Akademgorodok, Krasnoyarsk, 660036

A. Krolikov

Siberian Federal University

Email: diana.saykova@mail.ru
Rússia, Krasnoyarsk, 660041

E. Pikurova

Siberian Federal University; Institute of Chemistry and Chemical Engineering, Krasnoyarsk Scientific Center (Federal Research Center), Siberian Branch, Russian Academy of Sciences

Email: diana.saykova@mail.ru
Rússia, Krasnoyarsk, 660041; Akademgorodok, Krasnoyarsk, 660036

A. Samoilo

Siberian Federal University

Email: diana.saykova@mail.ru
Rússia, Krasnoyarsk, 660041

Bibliografia

  1. Литюк Л.М., Журавлев Г.И. Химия и технология ферритов: Учебное пособие для вузов. Л.: Химия, 1983. 256 с.
  2. Вест А. Химия твердого тела. Теория и приложения. М.: Мир, 1988. Ч. 1. 558 с.
  3. Преображенский А.А., Бишард Е.Г. Магнитные материалы и элементы. М.: Высш. шк., 1986. 256 с.
  4. Zangeneh H., Zinatizadeh A.A., Zinadini S. еt al. // Composites Part B. 2019. V. 176. P. 107158. https://doi.org/10.1016/j.compositesb.2019.107158
  5. An P., Zuo F., Li X. et al. // Nano. 2013. V. 8. № 6. P.1350061-1. https://doi.org/10.1142/S1793292013500616
  6. Iqbal A., Haq A. ul, Cerron-Calle G.A. et al. // Catalysts. 2021. V. 11. P. 806. https://doi.org/10.3390/catal11070806
  7. Shokri A. // Environ. Chall. 2021. V. 5. P. 100332. https://doi.org/10.1016/j.envc.2021.100332
  8. Arumugham N., Mariappan A., Eswaran J. et al. // J. Hazard. Mater. 2022. V. 8. P. 100156. https://doi.org/10.1016/j.hazadv.2022.100156
  9. Peymanfar R., Ramezanalizadeh H. // Optik. 2018. V. 169. P. 424. https://doi.org/10.1016/j.ijleo.2018.05.072
  10. Yang H., Zhang X., Weiqin A., Guangzhou Q. // Mater. Res. Bull. 2004. V. 39. № 6. P. 833.
  11. Azizi A., Sadrnezhaad S.K. // Ceram. Int. 2010. V. 36. № 7. P. 2241. https://doi.org/10.1016/j.ceramint.2010.06.004.
  12. Lisnevskaya I.V., Bobrova I.A., Lupeiko T.G. // J. Magn. Magn. Mater. 2016. V. 37. P. 86. https://doi.org/10.1016/j.jmmm.2015.08.084
  13. Лисневская И.В., Боброва И.А., Петрова А.В., Лупейко Т.Г. // Журн. неорган. химии. 2012. Т. 57. С. 474.
  14. Sivakumar P., Ramesh R., Ramanand A. et al. // Mater. Res. Bull. 2011. № 46. P. 2208. https://doi.org/10.1016/j.materresbull.2011.09.010
  15. Mana R., Raguram T., Rajni K.S. // Mater. Today: Proc. 2019. № 18. P. 1753.
  16. Кузнецов М.В., Морозов Ю.Г., Белоусова О.В. // Неорган. материалы. 2012. Т. 48. № 10. С. 1172.
  17. Hernandeza P.T., Kuznetsov M.V., Morozov I.G., Parkind I.P. // Mater. Sci. Eng., B. 2019. № 244. P. 81. https://doi.org/10.1016/j.mseb.2019.05.003
  18. Shafi K., Koltypin Y., Gedanken A. // J. Phys. Chem. B. 1997. V. 101. № 33. P. 6409.
  19. Fang J., Shama N., Tung L.D. // J. Appl. Phys. 2003. V. 93. № 10. P. 7483.
  20. Rodriguez-Rodriguez A.A., Moreno-Trejo M.B., Melendez-Zaragoza M.J. et al. // Int. J. Hydrogen Energy. 2018. V. 30. P. 12421. https://doi.org/10.1016/j.ijhydene.2018.09.183
  21. Елисеев А.А., Лукашин А.В. Функциональные наноматериалы. М.: Физматлит, 2010. 456 c.
  22. Udhayaa P.A., Bessy T.C., Meena M. // Mater. Today: Proceedings. 2019. V. 8. P. 169. https://doi.org/10.1016/j.matpr.2019.02.096
  23. Mapossa A.B., Dantas J., Silva M.R. // Arabian J. Chem. 2019. V. 30. P. 1. https://doi.org/10.1016/j.arabjc.2019.09.003
  24. Jifeng Q., Tinghua Ch., Shi L. et al. // Chin. Chem. Lett. 2019. V. 30. P. 1198. https://doi.org/10.1016/j.cclet.2019.01.021
  25. Morelos-Santos O., Reyes de la Torre A.I., Schacht-Hernandez P. et al. // Catal. Today. 2019. V. 329. P. 1. https://doi.org/10.1016/j.cattod.2019.10.012
  26. Zhang S., Jiang W., Li Y. et al. // Sens. Actuators, B. 2019. V. 291. P. 266. https://doi.org/10.1016/j.snb.2019.04.090
  27. Chen D.H., He X.R. // Mater. Res. Bull. 2001. № 36. P. 1369. https://doi.org/10.1016/S0025-5408(01)00620-1
  28. Hassan A., Khan M.A., Shahid M. et al. // J. Magn. Magn. Mater. 2015. V. 393. P. 56. https://doi.org/10.1016/j.jmmm.2015.05.033
  29. Velmurugan K., Venkatachalapathy V.S.K., Sendhilnathan S. // Mater. Res. 2010. V. 13. P. 299. https://doi.org/10.1590/S1516-14392010000300005
  30. Gadkari А.В., Shinde T.J., Vasambekar P.N. // J. Mater. Sci. – Mater. Electron. 2010. V. 21. P. 96. https://doi.org/10.1007/s10854-009-9875-6
  31. Maaz K., Karim S., Mumtaz A. et al. // J. Magn. Magn. Mater. 2009. № 321. P. 1838. https://doi.org/10.1016/j.jmmm.2008.11.098
  32. Трофимова Т.В., Сайкова С.В., Пантелеева М.В. и др. // Стекло и керамика. 2018. № 2. С. 38.
  33. Сайкова С.В., Трофимова Т.В., Павликов А.Ю., Самойло А.С. // Журн. неорган. химии. 2020. Т. 65. № 3. С. 287.
  34. Chen C.C., Liao H.J., Cheng C.Y. et al. // Biotechnol. Lett. 2007. V. 29. P. 391. https://doi.org/10.1007/s10529-006-9265-6
  35. Chen K.C., Wu J-Y., Huang C-C. et al. // J. Biotechnol. 2003. V. 101. P. 241. https://doi.org/10.1016/S0168-1656(02)00362-0
  36. Cho B.P., Yang T., Blankenship L.R. et al. // Chem. Res. Toxicol. 2003. V. 16. P. 285. https://doi.org/10.1021/tx0256679
  37. Saykova D., Saikova S., Mikhlin Yu. et al. // Metals. 2020. V. 10. № 1. P. 1075. https://doi.org/10.3390/met10081075
  38. Адлер Ю.П., Маркова Е.В., Грановский Ю.В. Планирование эксперимента при поиске оптимальных условий. М.: Наука, 1976. 280 с.
  39. Сайкова С.В., Немкова Д.И., Пикурова Е.В., Самойло А.С. // Журн. неорган. химии. 2023. Т. 68. № 8. С. 1011.
  40. CRC Handbook of Chemistry and Physics / Ed. Lide D.R. CRC Press, 2017. 2560 p.
  41. Yusmar A., Armitasari L., Suharyadi E. // Mater. Today: proceedings. 2018. V. 5. P. 14955. https://doi.org/10.1016/j.matpr.2018.04.037
  42. Sharifi I. // J. Magn. Magn. Mater. 2012. V. 324. № 15. P. 2397. https://doi.org/10.1016/j.jmmm.2012.03.008

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar
2. Fig. 1. The structural formula (a) and the electronic absorption spectrum (b) of crystalline violet.

Baixar (91KB)
Metadados
3. Fig. 2. Scheme of the installation for conducting a photocatalytic reaction.

Baixar (81KB)
Metadados
4. Fig. 3. Diffractograms of samples obtained in experiments 1-8: + — NiFe2O4, * — Fe2O3.

Baixar (200KB)
Metadados
5. Fig. 4. Diffractogram of sample 9 obtained under optimal conditions and calcined at 650 °C.

Baixar (69KB)
Metadados
6. Fig. 5. Micrography of TEM (a) and size distribution (b) of particles of sample 9 obtained under optimal conditions and calcined at 650 °C.

Baixar (139KB)
Metadados
7. 6. Diffractograms of composites obtained on the basis of NiFe2O4 and ZnO after firing at 800 °C: + – ZnxNi1–xFe2O4, * – ZnO, o – Fe2O3, ~ – unidentifiable X-ray reflexes.

Baixar (165KB)
Metadados
8. Fig. 7. Dependence of the lattice parameter of the spinel phase on the molar fraction of ZnO in composites based on NiFe2O4 and ZnO.

Baixar (53KB)
Metadados
9. Fig. 8. Change in the optical density of the crystalline violet solution (λmax = 590 nm) depending on the duration of the photocatalytic decomposition process: 1 – NiFe2O4, 2 – ZnFe2O4, 3 – sample K4, 4 – sample K3, 5 – sample K2, 6 – sample K5, 7 – sample K1.

Baixar (103KB)
Metadados
10. Fig. 9. The effect of the photocatalyst composition on the degree of destruction of crystalline violet (1 h).

Baixar (61KB)
Metadados

Declaração de direitos autorais © Russian Academy of Sciences, 2024