Synthesis and Structure of Cyclometallated Palladium Binuclear Complexes with Bridging Carboxylate Ligands

Yu. E. Makarevich; Макаревич Ю. Е.; M. N. Vargaftik; Варгафтик М. Н.; M. Yu. Nesterenko; Нестеренко М. Ю.; M. V. Panina; Панина М. В.; A. S. Popova; Попова А. С.; I. V. Skabitsky; Скабицкий И. В.; O. V. Sulimova; Сулимова О. В.; E. A. Sosunov; Сосунов Е. А.; N. K. Ogarkova; Огаркова Н. К.; I. A. Yakushev; Якушев И. А.

doi:10.31857/S0044457X2360127X

Synthesis and Structure of Cyclometallated Palladium Binuclear Complexes with Bridging Carboxylate Ligands

Autores: Makarevich Y.E.¹, Vargaftik M.N.¹, Nesterenko M.Y.¹, Panina M.V.¹, Popova A.S.¹, Skabitsky I.V.¹, Sulimova O.V.¹, Sosunov E.A.¹, Ogarkova N.K.¹, Yakushev I.A.¹
Afiliações:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Edição: Volume 68, Nº 9 (2023)
Páginas: 1244-1254
Seção: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://rjonco.com/0044-457X/article/view/666242
DOI: https://doi.org/10.31857/S0044457X2360127X
EDN: https://elibrary.ru/WKRLKU
ID: 666242

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Resumo

New bimetallic pivalate Pd(II) complex [PdNi(OOCtBu)4(HOOCtBu)] (I) has been synthesized from [PdNi(OOCMe)4] and used as a starting reagent in a further complexation reaction. Cyclometallated binuclear carboxylate palladium complexes [(OOCMe)Pd(2‑phpy)]2 (II) and [(OOCtBu)Pd(2‑phpy)]2 (III) have been obtained by the reaction between heterometallic compounds [Pd(OOCR)4Ni] (R = Me, tBu) and 2-phenylpyridine (2-phpy). The reaction proceeds at room temperature under mild conditions. All the compounds obtained have been isolated in crystalline form from a medium of nonpolar solvents, characterized by single-crystal X-ray diffraction analysis, and deposited at the Cambridge Crystallographic Data Center (CCDC nos. 2256606 for I, 2247942 for II, and 2247943 for III).

Palavras-chave

heterometallic complexes, palladium, cyclometalation, carboxylates, binuclear compounds, synthesis, 2-phenylpyridine, X-ray diffraction

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