Synthesis of C-mercuro derivatives of ortho-carborane. Crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury

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Resumo

Many carborane derivatives, first synthesized during the rapid development of this field of chemistry in the 60s of the last century, remained completely uncharacterized by modern spectral and structural methods. In this work, a series of C-mercuro derivatives of ortho-carborane 1-PhHg-2-Ph-1,2-C2B10H10 and (2-R-1,2-C2B10H10)2Hg (R = H, Me, Ph) were newly synthesized and characterized by NMR spectroscopy. The molecular crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury was determined by single crystal X-ray diffraction.

Sobre autores

S. Anufriev

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: sivaev@ineos.ac.ru
Rússia, Moscow

S. Timofeev

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: sivaev@ineos.ac.ru
Rússia, Moscow

D. Nasyrova

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; Moscow Institute of Physics and Technology

Email: sivaev@ineos.ac.ru
Rússia, Moscow; Dolgoprudny

I. Sivaev

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Plekhanov Russian University of Economics

Autor responsável pela correspondência
Email: sivaev@ineos.ac.ru
Rússia, Moscow; Moscow

V. Bregadze

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: sivaev@ineos.ac.ru
Rússia, Moscow

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Посвящается 125-летию со дня рождения академика А.Н. Несмеянова и 70-летию основания Института элементоорганических соединений Российской академии наук.


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