Luminescent Mn2+-Doped MgO–Al2O3–ZrO2–SiO2 Sol-Gel Materials

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In present work Mn2+-doped MgO-Al2O3-ZrO2-SiO2 materials were synthesized. Their structure, morphology, chemical composition and luminescent properties were studied using X-Ray diffraction, scanning electron microscopy, EDX analysis and luminecent spectroscopy. It was shown that the application of sol-gel method provides the high-volume homogeneity of chemical composition of synthesized materials. Introduction of Mn into the composition of sol-gel materials accelerates significantly the crystalization processes during the thermal treatment. In the luminescence spectra several groups of emission bands are observed. These bands are situated in blue and yellow-red part of spectrum. this phenomenon is related with incorporation of Mn2+ into the structure of different crystals formed during the thermal treatment of gels. Obtained materials can be perspective for application as luminophores in the lighting for plant production.

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Sobre autores

S. Evstropiev

Vavilov State Optical Institute; ITMO University; Saint Petersburg State Institute of Technology

Autor responsável pela correspondência
Email: evstropiev@bk.ru
Rússia, Saint Petersburg; Saint Petersburg; Saint Petersburg

V. Stolyarova

Institute of Silicate Chemistry of Russian Academy of Sciences; Saint Petersburg State University

Email: evstropiev@bk.ru
Rússia, Saint Petersburg; Saint Petersburg

A. Saratovskii

Saint Petersburg State Institute of Technology; Institute of Silicate Chemistry of Russian Academy of Sciences

Email: evstropiev@bk.ru
Rússia, Saint Petersburg; Saint Petersburg

D. Bulyga

Vavilov State Optical Institute; ITMO University

Email: evstropiev@bk.ru
Rússia, Saint Petersburg; Saint Petersburg

K. Dukelskii

Vavilov State Optical Institute; ITMO University; Bonch-Bruevich Saint Petersburg State University of Telecommunications

Email: evstropiev@bk.ru
Rússia, Saint Petersburg; Saint Petersburg; Saint Petersburg

N. Knyazyan

Armenian State Institute of Inorganic Chemistry

Email: evstropiev@bk.ru
Armênia, Yerevan

D. Yurchenko

Institute of Silicate Chemistry of Russian Academy of Sciences

Email: evstropiev@bk.ru
Rússia, Saint Petersburg

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2. Fig. 1. Illustrative Tanabe-Sugano diagram constructed on the basis of data [18, 20] and demonstrating the character of the influence of the crystal field strength of the nearest environment on the splitting of energy levels of Mn2+ ions.

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3. Fig. 2. X-ray diffraction patterns of sol-gel powders of the MgO-Al2O3-ZrO2-SiO2 system obtained from gel 1 containing no Mn (a) and from gel 2 containing Mn (b), heat-treated at different temperatures.

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4. Fig. 3. Electron microscopic images of Mn-free gel 1. Initial gel before heat treatment (a), gel 1, heat treated at 1150C (b).

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5. Fig. 4. Electron microscopic images of gel 2 containing Mn. Original gel before heat treatment (a), gel heat treated at 600 (b); 900 (c); 1150C (d).

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6. Fig. 5. (a) Emission (1-4) and luminescence excitation spectra (5, 6) of gel 2 heat-treated at 900C. Luminescence excitation wavelengths: 250 (1); 350 (2); 400 (3); 480 nm (4). Emission wavelengths: 560 (5); 640 nm (6). (b) Emission (1-5) and luminescence excitation (6) spectra of gel 2 heat-treated at 1150C. Luminescence excitation wavelength: 250 (1); 300 (2); 400 (3); 450 (4); 480 nm (5). Emission wavelength: 560 nm (6). (c) Difference emission spectra (excitation wavelength 350 (1) and 400 nm (2)) of gel 2, showing the changes in the emission spectra of the gel when the heat treatment temperature was increased from 900 to 1150С.

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