Synthesis and extraction properties of 4,5-diphosphorylated triazoles

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

A method for the synthesis of 4,5-diphosphorylated 1,2,3-triazoles has been developed, and the extraction of U(VI), Th(IV), and lanthanides(III) from nitric acid solutions by them was studied. A synergistic effect was found in the extraction of metal ions with mixtures of 4,5-diphosphorylated 1,2,3-triazoles and dinonylnaphthalenesulfonic acid. The stoichiometry of the extracted complexes was determined, and the influence of the structure of the extractant and the concentration of HNO3 in the aqueous phase on the efficiency of the extraction of metal ions into the organic phase was considered. It was established that 4,5-diphosphorylated 1,2,3-triazole with the octyl substituent at nitrogen atom has the highest extraction ability with respect to actinides and lanthanides in nitric acid media.

About the authors

A. N Turanov

Yu.A. Ossipyan Institute of Solid State Physics of the Russian Academy of Sciences

V. K Karandashev

Institute of Microelectronics Technology and High Pure Materials of the Russian Academy of Sciences

O. I Artyushin

A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

E. V Smirnova

A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Email: matveeva@gmail.com

V. K Brel

A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

References

  1. Myasoedov B.F., Kalmykov S.N., Kulyako Yu.M., Vinokurov S.E. // Geochem. Int. 2016. Vol. 54. N 13. P. 1156. doi: 10.1134/S0016702916130115
  2. Аляпишев М.Ю., Бабаин В.А., Устынюк Ю.А. // Усп. хим. 2016. Т. 85. № 9. С. 943
  3. Alyapychev M.Yu., Babain V.A., Ustynyuk Yu.A. // Russ. Chem. Rev. 2016. Vol. 85. N 9. P. 943. doi: 10.1070/RCR4588
  4. Leoncini A., Huskens J., Verboom W. // Chem. Soc. Rev. 2017. Vol. 46. P. 7229. doi: 10.1039/C7CS00574A
  5. Wilson A.M., Bailey P.J., Tasker P.A. // Chem. Soc. Rev. 2014. Vol. 43. P. 123. doi: 10.1039/C3CS60275C
  6. Werner E.J., Biros S.M. // Org. Chem. Front. 2019. Vol. 6. P. 2067. doi: 10.1039/C9QO00242A
  7. Bhattacharyya A., Mohapatra P.K. // Radiochim. Acta. 2019. Vol. 107. P. 931. doi: 10.1515/ract-2018-3064
  8. Розен А.М., Крупнов Б.В. // Усп. хим. 1996. Т. 65. № 11. С. 1052
  9. Rozen A.M., Krupnov B.V. // Rus. Chem. Rev. 1996. Vol. 65. N 11. P. 973. doi: 10.1070/RC1996v065n11ABEH000241
  10. Myasoedov B.F., Chmutova M.K., Kochetkova N.E., Koiro O.E., Pribylova G.A., Nesterova N.P., Medved T.Y., Kabachnik M.I. // Solv. Extr. Ion Exch. 1986. Vol. 4. N 1. P. 61. doi: 10.1080/07366298608917853
  11. Horwitz E.P., Martin K.A., Diamond H., Kaplan L. // Solv. Extr. Ion Exch. 1986. Vol. 4. N 3. P. 449. doi: 10.1080/07366298608917877
  12. Чмутова М.К., Литвина М.Н., Прибылова Г.А., Иванова Л.А., Смирнов И.В., Шадрин А.Ю, Мясоедов Б.Ф. // Радиохимия. 1999. Т. 41. № 4. С. 331.
  13. Siddall T.H. // J. Inorg. Nucl. Chem. 1963. Vol. 25. P. 883. doi: 10.1016/0022-1902(63)80376-0
  14. Mrochek J.E., Banks V.C. // J. Inorg. Nucl. Chem. 1965. Vol. 27. P. 589. doi: 10.1016/0022-1902(65)80265-2
  15. Розен А.М., Николотова З.И., Карташева Н.А., Юдина К.С. // Докл. АН СССР. 1975. Т. 222. № 5. С. 1151.
  16. Розен А.М., Николотова З.И., Карташева Н.А. // Радиохимия. 1986. Т. 28. № 3. С. 407.
  17. Беркман З.А., Бертина Л.Э., Кабачник М.И., Коссых В.Г., Медведь Т.Я., Нестерова Н.П., Розен А.М., Юдина К.С. // Радиохимия. 1975. Т. 17. № 2. С. 210.
  18. Розен А.М., Николотова З.И., Карташева Н.А., Медведь Т.Я., Нестерова Н.П., Юдина К.С., Кабачник М.И. // Радиохимия. 1976. Т. 18. № 6. С. 846.
  19. Matveeva A.G., Artyushin O.I., Pasechnik M.P., Stash A.I., Vologzhanina A.V., Matveev S.V., Godovikov I.A., Aysin R.R., Moiseeva A.A., Turanov A.N., Karandashev V.K., Brel V.K. // Polyhedron. 2021. Vol. 198. Article ID 115085. doi: 10.1016/j.poly.2021.115085
  20. Туранов А.Н., Карандашев В.К., Артюшин О.И., Костикова Г.В., Федосеев А.М., Брель В.К. // ЖОХ. 2022. Т. 92. № 8. С. 1289
  21. Turanov A.N., Karandashev V.K., Artyushin O.I., Kostikova G.V., Fedoseev A.M., Brel V.K. // Russ. J. Gen. Chem. 2022. Vol. 92. P. 1479. doi: 10.1134/S1070363222080163
  22. Turanov A.N., Karandashev V.K., Artyushin O.I., Brel V.K. // Solv. Extr. Ion Exch. 2020. Vol. 38. N 2. P. 166. doi: 10.1080/07366299.2019.1708001
  23. Konopkina E.A., Matveev P.I., Huang P.-W., Kirsanova A.A., Chernysheva M.G., Sumyanova T. B., Domnikov K.S., Shi W.-Q., Kalmykov S.N., Petrov V.G., Borisova N.E. // Dalton Trans. 2022. Vol. 51. P. 11180. doi 10.139/d2dt01007k
  24. Zakirova G.G., Matveev P.I., Mladentsev D.Yu., Evsiunina M.V., Tafeenko V.A., Borisova N.E. // Mendeleev Commun. 2019. Vol. 29. N 4. P. 463. doi: 10.1016/j.mencom.2019.07.037
  25. Matveev P.I., Borisova N.E., Andreadi N.G., Zakirova G.G., Petrov V.G., Belova E.V., Kalmykov S.N., Myasoedov B.F. // Dalton Trans. 2019. Vol. 48. P. 2554. doi: 10.1039/C8DT04729D
  26. Artyushin O.I., Vologzhanina A.V., Turanov A.N., Karandashev V.K., Brel V.K. // Mendeleev Commun. 2021. Vol. 31. P. 306. doi 10. 1016/j.mencom.2021.05.009
  27. Rheingolg A.L., Liable-Sands L.M., Trofimenko S. // Angew. Chem. Int. Ed. 2000. Vol. 39. P. 3321. doi 0.1002/1521-3773(20000915)39:18<3321::AID-ANIE3321>3.0.CO;2-V
  28. Moya-Cabrera M., Jancik V., Castro R.A., HerbstIrmer R., Roesky H.W. // Inorg. Chem. 2006. Vol. 45. P. 5167. doi: 10.1021/ic051567p
  29. Alcantara-Garsia J., Jancik V., Barroso J., Hidalgo-Bonilla S., Cea-Olivares R., Toscano R.A, Moya-Cabrera M. // Inorg. Chem. 2009. Vol. 48. P. 5874. doi: 10.1021/ic900166u
  30. Correa-Ascencio M., Galvan-Miranda E.K., Rascon-Cruz F., Jimenez-Sandoval O., Jimenez-Sandoval S.J., Cea-Olivares R., Jancik V., Toscano R.A, Garcia-Montalvo V. // Inorg. Chem. 2010. Vol. 49. P. 4109. doi: 10.1021/ic902120e
  31. Mukai H., Sohrin Y. // Inorg. Chim. Acta. 2009. Vol. 362. P. 4526. doi: 10.1016/j.ica.2009.06.01327
  32. Ramadan A., Mahmoud M., Khalifa S.M., Souka N. // J. Radioanal. Nucl. Chem. Lett. 1993. Vol. 176. P. 457. doi: 10.1007/bf02177682
  33. Туранов А.Н., Карандашев В.К., Яркевич А.Н. // Радиохимия. 2018. Т. 60. № 6. С. 520.
  34. Turanov A.N., Karandashev V.K. // Solv. Extract. Ion Exch. 2018. Vol. 36. P. 257. doi: 10.1060/07366299.1459157
  35. Danesi P.R., Chiarizia R., Scibona G. // J. Inorg. Nucl. Chem. 1973. Vol. 35. N 11. P. 3926. doi: 10.1016/0022-1902(73)80089-2
  36. Полянский К.Б., Афанасьев В.В., Беспалова Н.Б. Пат. RU 2616628 C2 (2017).
  37. Baek S.-Y., Kim Y.-W., Yoo S.-H., Chung K., Kim N.-K., Kim J.-S. // Ind. Eng. Chem. Res. 2012. Vol. 51. N 28. P. 9669. doi: 10.1021/ie300316f
  38. Smith Jr. R.H., Mehl A.F., Shantz Jr. D.L., Chmurny G.N., Michejda C.J. // J. Org. Chem. 1988. Vol. 53. N 7. P. 1467. doi: 10.1021/jo00242a022
  39. Artyushin O.I., Vorob'eva D.V., Vasil'eva T.P., Osipov S.N., Roeschenthaler G.-V., Odinets I.L. // Heteroatom Chem. 2008. Vol. 19. P. 293. doi: 10.1002/hc
  40. Tsvetkov E.N., Bondarenko N.A., Malakhova I.G., Kabachnik M.I. // Synthesis. 1986. N 3. P. 198. doi: 10.1055/s-1986-31510

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2023 Russian Academy of Sciences