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Abstract

С целью создания материалов с высоким массовым содержанием водорода, пригодных для использования в системах электроснабжения мобильных устройств на основе топливных элементов, выполнен синтез и проведено исследование свойств хранения и генерации водорода для композита на основе диаммиакатов боргидридов магния и цинка. Синтез выполнен методом механохимической обработки смеси Mg(BH4)2(NH3)2/Zn(BH4)2(NH3)2 в мольном соотношении 1:1. Образцы были проанализированы с использованием современных методов анализа: РФА, ИК-спектроскопии, СТА и РФЭС. Проведено термическое разложение композита и обнаружено снижение температуры выделения водорода по сравнению с исходными диаммиакатами. Кроме того, результаты исследования показали, что механизм реакции термического разложения композитов отличается от механизмов термолиза исходных комплексов.

About the authors

V. P. Vasiliev

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of RAS; Hydrogen Energy Center (PAO AFK Sistema)

Email: vvp@icp.ac.ru
142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 1; 142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 3

O. V. Kravchenko

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of RAS; Hydrogen Energy Center (PAO AFK Sistema)

Email: vvp@icp.ac.ru
142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 1; 142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 3

M. V. Solovev

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of RAS

Email: vvp@icp.ac.ru
142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 1

G. V. Shilov

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of RAS

Email: vvp@icp.ac.ru
142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 1

A. V. Shikhovtsev

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of RAS; Hydrogen Energy Center (PAO AFK Sistema)

Email: vvp@icp.ac.ru
142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 1; 142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 3

A. A. Zaytsev

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of RAS

Email: vvp@icp.ac.ru
142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 1

Y. A. Dobrovolsky

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of RAS; Hydrogen Energy Center (PAO AFK Sistema)

Author for correspondence.
Email: vvp@icp.ac.ru
142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 1; 142432, Московская обл., г. Черноголовка, пр. Академика Семенова, д. 3

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