Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands

A. V. Maleeva; Малеева А. В.; O. Yu. Trofimova; Трофимова О. Ю.; I. A. Yakushev; Якушев И. А.; R. R. Aysin; Айсин Р. Р.; A. V. Piskunov; Пискунов А. В.

doi:10.31857/S0132344X2260059X

Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands

Authors: Maleeva A.V.¹, Trofimova O.Y.¹, Yakushev I.A.², Aysin R.R.³, Piskunov A.V.¹
Affiliations:
1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
Issue: Vol 49, No 7 (2023)
Pages: 412-421
Section: Articles
URL: https://rjonco.com/0132-344X/article/view/667496
DOI: https://doi.org/10.31857/S0132344X2260059X
EDN: https://elibrary.ru/TVGOVB
ID: 667496

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Abstract

New heteroleptic zinc catecholate complexes based on 3,6-di-tert-butyl-o-benzoquinone and containing metal-coordinated N-donor ligands (2,2'-bipyridine and phenanthroline) were prepared by ligand exchange. According to X-ray diffraction data, both complexes were dimers with multiple intermolecular π–π interactions between the aromatic moieties of neighboring molecules (CCDC nos. 2222704 (I), 2222705 (II)). The electronic transmission spectra of crystalline samples of I and II and their solutions show broad absorption bands in the visible region with a maximum at about 500 nm.

Keywords

redox-active ligand, o-quinone, charge transfer, zinc, X-ray diffraction, electronic spectroscopy

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