New Uranyl Succinate-Containing Polymers: Synthesis and Structure

L. B. Serezhkina; Сережкина Л. Б.; M. S. Grigoriev; Григорьев М. С.; M. V. Sukacheva; Сукачева М. В.; E. F. Rogaleva; Рогалева Е. Ф.; V. N. Serezhkin; Сережкин В. Н.

doi:10.31857/S0132344X22600424

New Uranyl Succinate-Containing Polymers: Synthesis and Structure

Authors: Serezhkina L.B.¹, Grigoriev M.S.², Sukacheva M.V.¹, Rogaleva E.F.¹, Serezhkin V.N.¹
Affiliations:
1. Samara National Research University named after Academician S.P. Korolev, Samara, Russia
2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Issue: Vol 49, No 6 (2023)
Pages: 375-382
Section: Articles
URL: https://rjonco.com/0132-344X/article/view/667507
DOI: https://doi.org/10.31857/S0132344X22600424
EDN: https://elibrary.ru/UQDFFB
ID: 667507

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Abstract

Two uranyl succinate polymers, NH4[UO2(Suc)(HSuc)]∙H2O (I) and [UO2(Suc)(H2O)2] (II), where Suc = succinate ion (C4H4O2−4
), were synthesized and studied by X-ray diffraction, IR spectroscopy, and thermography (CCDC nos. 2202634 and 2202635, respectively). The main structural units in the crystals of I are infinite zigzag chains [UO2(Suc)(HSuc)]–, corresponding to the AQ02B01 crystal chemical formula (A = UO2+2,
Q02 = C4H4O2−4,
B01 = C4H5O−4
). It was established that in structure II, the electrically neutral [UO2(Suc)(H2O)2] chains correspond to the AQ02M12
crystal chemical formula (A = UO2+2,
Q02 = C4H4O2−4,
M1 = H2O). The intermolecular interactions in structures I and II were analyzed using the method of molecular Voronoi–Dirichlet polyhedra.

Keywords

uranyl complexes, succinate ions, crystal structure, Voronoi–Dirichlet polyhedral

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