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Structure and Thermal Characteristics of Bis(triethylammonium)-tetrakis(3,5-dinitro-2-pyridonato)cobalt(II)
- Authors: Nikiforova M.E.1, Kayumova D.B.1, Malkerova I.P.1, Alikhanyan A.S.1, Kiskin M.A.1, Sidorov A.A.1, Khoroshilov A.V.1, Dalinger I.L.2, Starosotnikov A.M.2, Bastrakov M.A.2, Eremenko I.L.1,3
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
- Issue: Vol 49, No 5 (2023)
- Pages: 290-297
- Section: Articles
- URL: https://rjonco.com/0132-344X/article/view/667512
- DOI: https://doi.org/10.31857/S0132344X22600333
- EDN: https://elibrary.ru/FZBCYX
- ID: 667512
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Abstract
The ionic compound [Co(OC5H2N(NO2)2)4]((C2H5)3NH)2 (I) was synthesized by the reaction of CoCl2·6H2O with 2-hydroxy-3,5-dinitropyridine in acetonitrile in the presence of triethylamine as a deprotonating agent. The structure of compound I was studied by X-ray diffraction (CCDC no. 2196071) and thermodynamic characteristics of I were determined.
About the authors
M. E. Nikiforova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: nikiforova.marina@gmail.com
Россия, Москва
D. B. Kayumova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: nikiforova.marina@gmail.com
Россия, Москва
I. P. Malkerova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: nikiforova.marina@gmail.com
Россия, Москва
A. S. Alikhanyan
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: nikiforova.marina@gmail.com
Россия, Москва
M. A. Kiskin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: nikiforova.marina@gmail.com
Россия, Москва
A. A. Sidorov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: nikiforova.marina@gmail.com
Россия, Москва
A. V. Khoroshilov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: nikiforova.marina@gmail.com
Россия, Москва
I. L. Dalinger
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: nikiforova.marina@gmail.com
Россия, Москва
A. M. Starosotnikov
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: nikiforova.marina@gmail.com
Россия, Москва
M. A. Bastrakov
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: nikiforova.marina@gmail.com
Россия, Москва
I. L. Eremenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
Author for correspondence.
Email: nikiforova.marina@gmail.com
Россия, Москва; Россия, Москва
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