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Iron Tricarbonyl Complexes Based on N,N'-Disubstituted Phenanthrenediimines
- Authors: Kazakov G.G.1,2, Druzhkov N.O.1, Baranov E.V.1, Cherkasov V.K.1,2
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Affiliations:
- Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
- Lobachevskii State University, Nizhny Novgorod, Russia
- Issue: Vol 49, No 3 (2023)
- Pages: 131-137
- Section: Articles
- URL: https://rjonco.com/0132-344X/article/view/667522
- DOI: https://doi.org/10.31857/S0132344X22600205
- EDN: https://elibrary.ru/CTUFOK
- ID: 667522
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Abstract
The oxidative addition of N,N'-disubstituted phenanthrenediimines to iron carbonyls was studied. The reactions of acceptor phenanthrenediimines with Fe2(CO)9 give iron(I) tricarbonyl complexes with anion-radical forms of the ligands. The synthesized compounds were characterized by NMR and IR spectroscopy. The structures of the complex based on N,N'-bis(3-trifluoromethylphenyl)phenanthrenediimine and imidazol-2-one ligand was established by X-ray diffraction (XRD) (CIF files СCDC nos. 2173471 and 2173472, respectively).
Keywords
About the authors
G. G. Kazakov
Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia; Lobachevskii State University, Nizhny Novgorod, Russia
Email: gkazakov@iomc.ras.ru
Россия, Нижний Новгород; Россия, Нижний Новгород
N. O. Druzhkov
Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
Email: gkazakov@iomc.ras.ru
Россия, Нижний Новгород
E. V. Baranov
Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
Email: gkazakov@iomc.ras.ru
Россия, Нижний Новгород
V. K. Cherkasov
Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia; Lobachevskii State University, Nizhny Novgorod, Russia
Author for correspondence.
Email: gkazakov@iomc.ras.ru
Россия, Нижний Новгород; Россия, Нижний Новгород
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