Synthesis of (η 6 -Arene)tricarbonylchromium Complexes of 1,3-Benzodioxanes

N. Yu. Grishina; Гришина Н. Ю.; E. V. Sazonova; Сазонова Е. В.; P. S. Ushakova; Ушакова П. С.; N. V. Somov; Сомов Н. В.; E. A. Medvedeva; Медведева Е. А.; A. Yu. Shishkin; Шишкин А. Ю.; A. N. Artemov; Артемов А. Н.

doi:10.31857/S0132344X24080012

Synthesis of (η⁶-Arene)tricarbonylchromium Complexes of 1,3-Benzodioxanes

Authors: Grishina N.Y.¹, Sazonova E.V.¹, Ushakova P.S.¹, Somov N.V.¹, Medvedeva E.A.¹, Shishkin A.Y.¹, Artemov A.N.¹
Affiliations:
1. Lobachevsky National Research State University
Issue: Vol 50, No 8 (2024)
Pages: 471-483
Section: Articles
URL: https://rjonco.com/0132-344X/article/view/667579
DOI: https://doi.org/10.31857/S0132344X24080012
EDN: https://elibrary.ru/MRLDZR
ID: 667579

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Abstract

The reactions of triamminotricarbonylchromium (I) with 1,3-benzodioxane (L¹), 2-methyl-1,3-benzodioxane (L²), and 2-phenyl-1,3-benzodioxane (L³) afford new complexes: (η⁶-C₈H₈O₂)Cr(CO)₃ (II), exo- and endo-[2-Me-(η⁶-C₈H₇O₂)]Cr(CO)₃ (III, IV), exo- and endo-[2-Ph-(η⁶-C₈H₇O₂)]Cr(CO)3 (V, VI), [2-(η⁶-Ph)-C₈H₇O₂]Cr(CO)₃ (VII), and endo-[2-(η⁶-Ph)]Cr(CO)₃-[η⁶-C₈H₇O₂]Cr(CO)₃ (VIII). The structures, compositions, and purity of the synthesized products are proved by UV, IR, and 1H NMR spectroscopy, HPLC, and mass spectrometry. The molecular structures of complexes IV–VI are determined by XRD (CIF files CCDC nos. 2263301 (IV), 2295552 (V), and 2237106 (VI)). A possibility of coordination of the tricarbonylchromium group at different sides of the phenylene ring of ligands L2 and L3 and on the phenyl substituent of ligand L³ is shown.

Keywords

heterocyclic compounds, (arene)tricarbonylchromium complexes, 1, 3-benzodioxane, diastereomers, regioisomers

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