Template Synthesis of the Iron(III) Complex with the Ligands Based on Acylpyrazolonepyridines

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Abstract

The reaction of new bidentate ligand, 1-(5-hydroxy-1-methyl-3-(pyridin-2-yl)-1Н-pyrazol-4-yl)ethan-1-one (L), with iron(III) chloride affords the mononuclear iron(III) complex FeL₂Cl₃, which is characterized by XRD (CIF file CCDC no. 2309481). The intramolecular hydrogen bond between the protonated pyridyl and acetyl groups in ligand L, which exists in the crystal as a zwitterion, provides the formation of rarely met iron complexes in which the β-diketonate fragment coordinates via the η1 mode. A similar coordination mode along with a possibility of a more favorable η2 coordination provides new possibilities for the design of heteropolynuclear compounds of various structures used in the fabrication of molecular devices of data storage and processing.

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About the authors

D. D. Strunin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Moscow State University

Email: igornikovskiy@mail.ru
Russian Federation, Moscow; Moscow

I. A. Nikovskii

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Author for correspondence.
Email: igornikovskiy@mail.ru
Russian Federation, Moscow

A. A. Dan´shina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Moscow Institute of Physics and Technology (National Research University)

Email: igornikovskiy@mail.ru
Russian Federation, Moscow; Dolgoprudnyi, Moscow oblast

Yu. V. Nelyubina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: igornikovskiy@mail.ru
Russian Federation, Moscow

References

  1. Sato O. // Nat. Chem. 2016. V. 8. P. 644. https://doi.org/10.1038/nchem.2547
  2. Sun Y., Rogers J. A. // Adv. Mat. 2007. V. 19. № 15. P. 1987. https://doi.org/10.1002/adma.200602223
  3. Mitzi D.B., Chondroudis K., Kagan C.R. // IBM J. Res. Dev. 2001. V. 45. № 1. P. 29. https://doi.org/10.1147/rd.451.0029
  4. Evangelio E., Ruiz-Molina D. // J. Eur. Inorg. Chem. 2005. V. 2005. № 15. P. 2957. https://doi.org/10.1002/ejic.200500323
  5. Tezgerevska T. Rousset E., Gable R.W. et al. // Dalton Trans. 2019. V. 48. № 31. P. 11674. https://doi.org/10.1039/C9DT02372K
  6. Calzolari A., Chen Y., Lewis G.F. et al. // J. Phys. Chem. B. 2012. V. 116. P. 13141. https://doi.org/10.1021/jp3099895
  7. Senthil Kumar K., Ruben M. // Coord. Chem. Rev. 2017. V. 346. № 1. P.176. https://doi.org/10.1016/j.ccr.2017.03.024
  8. Hogue R.W., Singh S., Brooker S. // Chem. Soc. Rev. 2018. V. 47. № 19. P. 7303. https://doi.org/10.1039/C7CS00835J
  9. Vieru V., Pasatoiu T.D., Ungur L. et al. // Inorg. Chem. 2016. V. 55. № 19. P. 12158. https://doi.org/10.1021/acs.inorgchem.6b01669
  10. Yamaguchi T., Sunatsuki Y., Ishida H., et al. // Inorg. Chem. 2008. V. 47. № 13. P. 5736. https://doi.org/10.1021/ic8000575
  11. Bala S., Bishwas M.S., Pramanik B. et al. // Inorg. Chem. 2015. V. 54. № 17. P. 8197. https://doi.org/10.1021/acs.inorgchem.5b00334
  12. Vujkovic N., César V., Lugan N., et al. // Chem. — Eur. J. 2011. V. 17. № 47. P. 13151. https://doi.org/10.1002/chem.201102767
  13. Cingolani A., Marchetti,F.. Pettinari C. et al. // Polyhedron 2006. V. 25. № 1. P. 124. https://doi.org/10.1016/j.poly.2005.07.020
  14. Bochkarev L.N., Bariniva Y.P., Ilicheva A.I. et al. // Inorganica Chim. Acta 2015. V. 425. № 30. P. 189. https://doi.org/10.1016/j.ica.2014.10.014
  15. Sherwood R., Gonzalez de Rivera F., Wan, J. H. et al. Inorg. Chem. 2015. V. 54. № 9. P. 4222. https://doi.org/10.1021/ic5028527
  16. Pettinari C., Caruso F., Zaffaroni N. // J. Inorg. Biochem. 2006. V. 100. № 1. P. 58. https://doi.org/10.1016/j.jinorgbio.2005.10.002
  17. Marchetti F., Pettinari R,; Pettinari C. // Coord. Chem. Rev. 2015. V. 303. № 1. P. 1. https://doi.org/10.1016/j.ccr.2015.05.003
  18. Marchetti F., Pettinari C., Di Nicola C. // Appl. Catal. Gen. 2010. V. 378. № 2. P. 211. https://doi.org/10.1016/j.apcata.2010.02.022
  19. Hasanzadeh Esfahani M., Behzad M., Dusek M. et al. // Inorganica Chim. Acta 2020. V. 508. № 1. P. 119637. https://doi.org/10.1016/j.ica.2020.119637
  20. Li Y., Guo J., Liu A. // RSC Adv. 2017. V. 7. № 16. P. 9847. https://doi.org/10.1039/C6RA27937F
  21. O´Brien, D.F., Gates J.W.Jr. // J. Org. Chem. 1966. V. 31. № 5. P. 1538. https://doi.org/10.1021/jo01343a054
  22. Kayode, G.O.; Montemore, M.M. // J. Mater. Chem. A. 2021. V. 9. № 39. P. 22325. https://doi.org/10.1039/D1TA06453C
  23. Halcrow M.A. Spin-Crossover Materials: Properties and Applications. Oxford (UK): Wiley, 2013.
  24. Demaison J., Császár A.G. // J. Mol. Struct. 2012. V. 1023. № 12. P. 7. https://doi.org/10.1016/j.molstruc.2012.01.030
  25. Lide D.R. // Tetrahedron 1962. V. 17. № 3–4. P. 125. https://doi.org/10.1016/S0040-4020(01)99012-X
  26. Alvarez, S. // Chem. Rev. 2015. V. 115. № 24. P. 13447. https://doi.org/10.1021/acs.chemrev.5b00537
  27. Omotowa B.A., Mesubi M.A. // Appl. Organomet. Chem. 1997. V. 11. № 1. P. 1. https://doi.org/10.1002/(SICI)1099-0739(199701)11:1<1::AID-AOC518>3.0.CO;2-3

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7. Fig. 1. General view of the FeL₂Cl₃ complex with atoms represented by thermal vibration ellipsoids (p = 50%). The complex occupies a special position in the crystal — a second-order axis passing through the iron(III) ion and the chloride anion Cl(1) coordinated to it. The minor disorder component with a population of <3% is not shown, and the numbering is given only for symmetrically independent atoms.

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