Mononuclear nickel(II) and copper(II) coordination compounds with ligands based on acetyl(benzoyl)acetone S-methylisothiosemicarbazones and 8-quinolinecarboxaldehyde. Synthesis and crystal structure

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Abstract

Template condensation of S-methylisothiosemicarbazones of acetyl- or benzoylacetone with 8-quinolinecarboxaldehyde in the presence of nickel(II) and copper(II) ions gave four new mononuclear coordination compounds [NiL1]I (I), [CuL1I] (II), [NiL2]I (III) и [CuL2I] (IV). The chemical composition of the products was confirmed by elemental analysis, IR spectroscopy, and mass spectrometry, and the crystal structure of compounds I and II was determined by X-ray diffraction analysis (CCDC no. 2266386, 2266387). X-ray diffraction study revealed a square planar coordination environment of the central ion of the cationic Ni(II) complex and square pyramidal geometry for the molecular Cu(II) complex.

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About the authors

M. А. Cocu

Moldova State University

Email: pavlina.bourosh@ifa.md

Institute of Chemistry

Moldova, Republic of, Chisinau

P. N. Bourosh

Moldova State University

Author for correspondence.
Email: pavlina.bourosh@ifa.md

Institute of Applied Physics

Moldova, Republic of, Chisinau

V. K. Kravtsov

Moldova State University

Email: pavlina.bourosh@ifa.md

Institute of Applied Physics

Moldova, Republic of, Chisinau

О. S. Danilescu

Moldova State University; Technical University of Moldova,

Email: pavlina.bourosh@ifa.md

Institute of Chemistry

Moldova, Republic of, Chisinau; Chisinau

I. I. Bulhac

Moldova State University

Email: pavlina.bourosh@ifa.md

Institute of Chemistry

Moldova, Republic of, Chisinau

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Supplementary files

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2. Scheme 1. Synthesis of complexes I-IV.

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3. Fig. 1. Molecular structure of ionic complex I.

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4. Fig. 2. Fragment of the component packaging in I.

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5. Fig. 3. Molecular structure of complex II.

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6. Fig. 4. Fragment of the crystal structure II.

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