Two- and Three-Dimensional Polymeric Co(II) Terephthalates with 3,3',5,5'-Tetrabromo-4,4'-bipyridine (3,3'5,5'-BrBipy)

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Abstract

The reaction of 3,3',5,5'-tetrabromo-4,4'-bipyridine (BrBipy) with cobalt nitrate and terephthalic acid (H2Bdc) gave 2D and 3D metal-organic frameworks {[Co2(Bdc)2(BrBipy)2(H2O)4] · 4DMF} (I) and {[Co2(Ddc)4(BrDipy)] · · 2MeOH} (II), respectively. The structure of the complexes was studied by X-ray diffraction (CCDC nos. 2259216 (I) and 2259214) (II)).

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About the authors

I. F. Sakhapov

South Ural State University; Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: adonin@niic.nsc.ru
Russian Federation, Chelyabinsk; Kazan

A. A. Zagidullin

Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences; Kazan (Volga Region) Federal University

Email: adonin@niic.nsc.ru

Alexander Butlerov Institute of Chemistry

Russian Federation, Kazan; Kazan

D. R. Islamov

Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences; Kazan (Volga Region) Federal University

Email: adonin@niic.nsc.ru

Alexander Butlerov Institute of Chemistry

Russian Federation, Kazan; Kazan

V. V. Sharutin

South Ural State University

Email: adonin@niic.nsc.ru
Russian Federation, Chelyabinsk

D. G. Yakhvarov

Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences; Kazan (Volga Region) Federal University

Email: adonin@niic.nsc.ru

Alexander Butlerov Institute of Chemistry

Russian Federation, Kazan; Kazan

D. A. Zherebtsov

South Ural State University

Email: adonin@niic.nsc.ru
Russian Federation, Chelyabinsk

V. A. Milyukov

Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences

Email: adonin@niic.nsc.ru
Russian Federation, Kazan

A. S. Zaguzin

South Ural State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: adonin@niic.nsc.ru
Russian Federation, Chelyabinsk; Novosibirsk

V. P. Fedin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk

S. A. Adonin

South Ural State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: adonin@niic.nsc.ru
Russian Federation, Chelyabinsk; Novosibirsk; Irkutsk

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Supplementary files

Supplementary Files
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2. Fig. 1. Fragment of the molecular structure I. Hereafter, Co is black, O is red, Br is olive, C is gray, N is blue. For some ligands, only donor atoms are shown.

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3. Fig. 2. Layers {[Co2Bdc4]} in structure II. Bis-pyridyl ligands are not displayed.

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4. Fig. 3. Three-dimensional structure II.

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