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Rhenium(V) Tris(pyrazolyl)borate Thiolate Complex with the Disulfide Bridging Ligand: Synthesis and Structure
- Authors: Skabitskii I.V.1, Shapovalov S.S.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Issue: Vol 50, No 2 (2024)
- Pages: 138-144
- Section: Articles
- URL: https://rjonco.com/0132-344X/article/view/667622
- DOI: https://doi.org/10.31857/S0132344X24020087
- EDN: https://elibrary.ru/ORENPO
- ID: 667622
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Abstract
The reaction of TpReOCl(StBu) (Tp = tris(pyrazolyl)borate anion) with sodium disulfide in dimethoxyethane affords the new binuclear rhenium complex [TpReO(μ-StBu)]2(μ-S2) (I). Complex I can also be synthesized by the reaction of TpReO(StBu)2 with a suspension of manganese(II) bromide in toluene accompanied by the dealkylation of one of the ligands to form one more new complex [TpReO]2(μ-S2)(μ-S) (II) containing the bridging sulfide and disulfide ligands. The structures of two crystalline solvates of complex I with dichloromethane containing the molecules with different conformations of the Re2S2 fragment (Ia and Ib) and complex II are studied by X-ray diffraction (XRD) (CIF files ССDC nos. 2262677, 2262678, and 2267423 for Ia, Ib, and II, respectively).
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About the authors
I. V. Skabitskii
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: skabitskiy@gmail.com
Russian Federation, Moscow
S. S. Shapovalov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: skabitskiy@gmail.com
Russian Federation, Moscow
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