Synthesis and structure of water-soluble complexes of copper fumarate and succinate with monoethanolamine

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Abstract

New water-soluble copper(II) complexes with dicarboxylic acids were obtained by the heterogeneous reaction of copper hydroxy carbonate with succinic or fumaric acid in water at 50°C. The additional introduction of monoethanolamine (MEA) into the complexes ensured high solubility of copper succinate and fumarate. The structures of the complexes [Cu(Suc) · 2MEA] · H2O and [Cu(Fum) · 2MEA] · H2O were studied by X-ray diffraction (CCDC nos. 2352578 and 2352579, respectively). The compounds were found to have a polymeric structure composed of zigzag chains.

About the authors

B. I. Petrov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: bip@iomc.ras.ru
Russian Federation, Nizhny Novgorod

V. V. Semenov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: bip@iomc.ras.ru
Russian Federation, Nizhny Novgorod

N. M. Lazarev

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: bip@iomc.ras.ru
Russian Federation, Nizhny Novgorod

E. V. Baranov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: bip@iomc.ras.ru
Russian Federation, Nizhny Novgorod

M. A. Lopatin

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: bip@iomc.ras.ru
Russian Federation, Nizhny Novgorod

References

  1. O’Connor B.H., Maslen E.N. // Acta Crystallogr. 1966. V. 20. P. 824.
  2. Bassi P.S., Chopra G.S., Gupta B.R. // Thermochim. Acta. 1988. V. 124. P. 197.
  3. Ghoshal D., Ghosh A.K., Mostufa G. et al. // Inorg. Chim. Acta. 2007. V. 360. № 5. P. 1771.
  4. Caires F.J., Lima L.S., Carvalho C.T. et al. // Thermochim. Acta. 2010. V. 500. P. 6.
  5. Юданова Л.И., Логвиненко В.А., Юданов Н.Ф. и др. // Неорган. материалы. 2014. Т. 50. № 9. С. 1022 (Yudanova L.I., Logvinenko V.A., Yudanov N.F. et al. // Inorg. Mater. 2014. V. 50. P. 945). https://doi.org/10.1134/S0020168514090180
  6. Carr N.J., Galwey A.K. // Faraday Trans. 1. 1988. V. 84. P. 1357.
  7. Inoue M., Kawaji H., Tojo T. et al. // Thermochim. Acta. 2005. V. 431. P. 58.
  8. Ying M., Yang G., Xu Y. et al. // Analyst. 2022. V. 147. P. 40.
  9. Prout C.K., Carruthers J.R., Rossotti F.J.C. // J. Chem. Soc. A. 1971. P. 3342.
  10. Sobel S., Haigney A., Kim M. et al. // Chem. Spec. Bioavailab. 2010. V. 22. P. 109.
  11. Kondratenko Y., Zolotarev A.A., Ignatyev I. et al. // Transition Met. Chem. 2020. V. 45. P. 71.
  12. Batool S.S., Gilani S.R., Zainab S.S. et al. // J. Coord. Chem. 2020. V. 73. P. 1778.
  13. Скорик Н.А., Васильева О.А. // Журн. неорган. химии. 2023. Т. 68. № 4. С. 529 (Skorik N.A., Vasil’eva O.A. // Russ. J. Inorg. Chem. 2023. V. 68. P. 458. https://doi.org/10.1134/S0036023623600211
  14. Yao Y.W., Xin W., Qi Z.S. // Transition Met. Chem. 2002. V. 27. P. 481.
  15. Padmanabhan M., Kumary S.M., Huang X. et al. // Inorg. Chim. Acta. 2005. V. 358. P. 3537.
  16. Gonzalez Garmendis M.J., San Nacianceno V., Seco J.M. et al. // Acta Cryst. C. 2009. V. 65. P. m436.
  17. Thebo K.H., Shad H.A., Malik M.A. et al. // J. Mol. Struct. 2010. V. 970. P. 75.
  18. Юданова Л.И., Логвиненко В.А., Юданов Н.Ф. и др. // Коорд. химия. 2013. Т. 39. № 5. С. 309 (Yudanova L.I., Logvinenko V.A., Yudanov N.F. et al. // Russ. J. Coord. Chem. 2013. V. 39. P. 415). https://doi.org/10.1134/S1070328413050102
  19. Юданова Л.И., Логвиненко В.А., Корольков И.В. и др. // Журн. физ. химии. 2018. Т. 92. № 11. С. 1753 (Yudanova L.I., Logvinenko V.A., Korol’kov I.V. et al. // Russ. J. Phys. Chem. 2018. V. 92. № 11. P. 2247). https://doi.org/10.1134/S003602441811047X
  20. Ganguly A., Ahmad T., Ganguli A.K. // Dalton Trans. 2009. P. 3536.
  21. Семенов В.В., Золотарева Н.В., Новикова О.В. и др. // Изв. АН. Сер. хим. 2022. Т. 71. № 5. С. 980 (Semenov V.V., Zolotareva N.V., Novikova O.V. et al. // Russ. Chem. Bull. 2022. V. 71. P. 980). https://doi.org/10.1007/s11172-022-3500-8
  22. Data Collection, Reduction and Correction Program, CrysAlisPro 1.171.41.93а — Software Package, Rigaku OD, 2020.
  23. SCALE3 ABSPACK: Empirical absorption correction, CrysAlisPro 1.171. 41.93а — Software Package, Rigaku OD, 2020.
  24. Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3.
  25. Sheldrick G.M. SHELXTL. Version 6.14. Structure Determination Software Suite; Madison (WI, USA): Bruker AXS, 2003.
  26. Sheldrick G.M. // Acta Crystallogr. С. 2015. V. 71. P. 3.
  27. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Cryst. 2009. V. 42. P. 339.
  28. Золотарева Н.В., Семенов В.В., Петров Б.И. // Журн. орган. химии. 2013. Т. 83. № 11. С. 1781 (Zolotareva N.V., Semenov V.V., Petrov B.I. // Russ. J. Gen. Chem. 2013. V. 83. P. 1985). https://doi.org/10.1134/S1070363213110030
  29. Fachini L.G., Baptistella G.B., Postal K. // RSC Adv. 2023. V. 13. P. 27997.
  30. Hathaway B.J., Billing D.E. // Coord. Chem. Rev. 1970. V. 5. № 2. P. 143.
  31. Гордон А., Форд Р. Спутник химика. М.: Мир, 1976. 245 с.

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