Complexes of Cu(II), Co(II), and Zn(II) Terephthalates with Hydroxyalkylamines

D. A. Zav’yalova; Завьялова Д. А.; Yu. A. Kondratenko; Кондратенко Ю. А.; A. A. Zolotarev; Золотарев А. А.; V. L. Ugolkov; Уголков В. Л.; T. A. Kochina; Кочина Т. А.

doi:10.31857/S0132344X22600655

Complexes of Cu(II), Co(II), and Zn(II) Terephthalates with Hydroxyalkylamines

Autores: Zav’yalova D.A.¹^,2, Kondratenko Y.A.¹, Zolotarev A.A.³, Ugolkov V.L.¹, Kochina T.A.¹
Afiliações:
1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, Russia
2. St. Petersburg State Technological Institute (Technical University), St. Petersburg, Russia
3. Institute of Earth Sciences, St. Petersburg State University, St. Petersburg, Russia
Edição: Volume 49, Nº 8 (2023)
Páginas: 474-484
Seção: Articles
URL: https://rjonco.com/0132-344X/article/view/667489
DOI: https://doi.org/10.31857/S0132344X22600655
EDN: https://elibrary.ru/SALKEI
ID: 667489

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Resumo

The reactions of Cu(II), Co(II), and Zn(II) terephthalates with hydroxyalkylamines (tris(2-hydroxyethyl)amine, bis(2-hydroxyethyl)amine, tris(hydroxymethyl)aminomethane, and bis(2-hydroxyethyl)aminotris(hydroxymethyl)methane) are studied for the first time. The structures and properties of the synthesized complexes are studied by IR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental and thermal analyses. The structure of the binuclear heteroligand [Cu2(TEA)2(Tph)]n·H2O complex is studied by single-crystal X-ray diffraction (XRD) (CIF file CCDC no. 2224437).

Palavras-chave

metal-organic frameworks, coordination polymers, hydrometallatranes, hydroxyalkylamines, terephthalic acid, crystal structure

Bibliografia

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