Palladium Complexes of Pyrimidine-2-thiones: Synthesis, Structures, and Properties

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

Complexes [PdL2Cl2] (I) and [PdL2Вr2] (II) (L is 5-acetyl-6-methyl-4-(3-nitrophenyl)-1,2,3,4-tetrahydropyrimidine-2-thione) are synthesized and characterized by spectral methods (1Н, 13С NMR and IR spectroscopy). The crystal structure of complex I is determined (CIF file ССDС no. 2233053) in which the palladium atom is coordinated by two halide ions and two sulfur atoms of two ligands L in a distorted square planar geometry. The catalytic activity of the synthesized palladium(II) complexes in the model epoxidation of allyl alcohol is estimated in comparison with the catalytic activity of the corresponding palladium halides and titanium-containing zeolite TS-1.

Sobre autores

A. Kuzovlev

Moscow State University; Tyumen State University

Autor responsável pela correspondência
Email: a.s.kuzovlev@gmail.com
Rússia, Moscow; Tyumen

N. Gordeeva

Russian Technological University (MIREA)

Email: a.s.kuzovlev@gmail.com
Rússia, Moscow

Zh. Pastukhova

Russian Technological University (MIREA)

Email: a.s.kuzovlev@gmail.com
Rússia, Moscow

V. Chernyshev

Moscow State University; Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: a.s.kuzovlev@gmail.com
Rússia, Moscow; Moscow

G. Buzanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: a.s.kuzovlev@gmail.com
Rússia, Moscow

S. Dunaev

Moscow State University

Email: a.s.kuzovlev@gmail.com
Rússia, Moscow

L. Bruk

Russian Technological University (MIREA)

Email: a.s.kuzovlev@gmail.com
Rússia, Moscow

Bibliografia

  1. Kokina T.E., Glinskaya L. A., Sheludyakova L. A. et al. // Polyhedron. 2019. V. 163. P. 121.
  2. Moro A.C., Mauro A. E., Netto A. V.G. et al. // Eur. J. Med. Chem. 2009. V. 44. № 11. P. 4611.
  3. Nadeem S., Bolte M., Ahmad S. et al. // Inorg. Chim. Acta. 2010. V. 363. № 13. P. 3261.
  4. Rohini G., Ramaiah K., Aneesrahman K. N. et al. // Appl. Organomet. Chem. 2018. V. 32. № 12. P. 4567.
  5. Da Silva D. L., Reis F. S., Muniz D. R. et al. // Bioorg. Med. Chem. 2012. V. 20. № 8. P. 2645.
  6. Sashidhara K.V., Avula S. R., Sharma K. et al. // Eur. J. Med. Chem. 2013. V. 60. P. 120.
  7. Kuzovlev A.S., Volkova D. A., Parfenova I. V. et al. // New J. Chem. 2020. V. 44. P. 7865.
  8. Kappe C.O. // Eur. J. Med. Chem. 2000. V. 35. P. 1043.
  9. Sati B. E., Sati H., Nargund L. V.G et al. // Orient. J. Chem. 2012. V. 28. № 2. P. 1055.
  10. Chikhale R., Thorat S., Pant A. et al. // Bioorg. Med. Chem. 2015. V. 23. № 20. P. 6689.
  11. Sawant R.L., Sarode V. I., Jadha G. D. et al. // Med. Chem. Res. 2011. V. 21. № 8. P. 1825.
  12. Kwon O.W., Moon E., Chari M. A. et al. // Bioorg. Med. Chem. Lett. 2012. V. 22. № 16. Р. 5199.
  13. Shkurko O.P., Tolstikova T. G., Sedova V. F. // Rus. Chem. Rev. 2016. V. 85. № 10. P. 1056.
  14. Lauro G., Strocchia M., Terracciano S. et al. // Eur. J. Med. Chem. 2014. V. 80. P. 407.
  15. Crespo A., El Maatougui A., Biagini P. et al. // ACS Med. Chem. Lett. 2013. V. 4. № 11. P. 1031.
  16. Cepeda V., Fuertes M., Castilla J. et al. // Anti-Cancer Agents Med. Chem. 2007. V. 7. № 1. P. 3.
  17. Alderden R.A., Hall M. D., Hambley T. W. // J. Chem. Ed. 2006. V. 83. № 5. P. 728.
  18. Kartalou, M. Essigmann, J.M. // Mut. Res. 2001. V. 478. № 1–2. Р. 23.
  19. De Moura T. R., Cavalcanti S. L., Sakamoto-Hojo E.T. et al. // Transition Met. Chem. 2017. V. 42. № 6. P. 565.
  20. Dorairaj D.P., Haribabu J., Hsu S. C.N. et al. // Inorg. Chem. Commun. 2021. V. 134. P. 109018.
  21. Dorairaj D.P., Haribabu J., Chithravel V. et al. // Res. Chem. 2021. V. 3. P. 100157.
  22. Bharati P., Bharti A., Nath P. et al. // Inorg. Chim. Acta. 2016. V. 443. P. 160.
  23. Pearson R.G. // Phys. Inorg. Chem. 1963. V.85. № 22. P. 3533.
  24. Ruan J., Xiao J. // Acc. Chem. Res. 2011. V. 44. № 8. Р. 614.
  25. Sherwood J., Clark J. H., Fairlamb I. J.S. et al. // Green Chem. 2019. V. 21. P. 2164.
  26. Gadge S.T., Bhanage B. M. // RSC Adv. 2014. V. 4. P. 10367.
  27. Wang D., Weinstein A. B., White P. B. et al. // Chem. Rev. 2018. V. 118. № 5. P. 2636.
  28. Engle K.M., Yu J-Q. // J. Org. Chem. 2013. V. 78. P. 8927.
  29. Zhang L-M., Li H-Y., Li H-X. et al. // Inorg. Chem. 2017. V. 56. P. 11230.
  30. Jia W-G., Gao L-L, Wang Z-B. et al. // RSC Adv. 2017. V. 7. P. 42792.
  31. Chernyshev V.V. // Russ. Chem. Bull. Int. Ed. 2001. V. 50. P. 2273.
  32. Cerny R. // Crystals. 2017. V. 7. P. 142.
  33. Hughes C.E., Reddy G. N.M., Masiero S. et al. // Chem. Sci. 2017. V. 8. P. 3971.
  34. Pawley G.S. // J. Appl. Crystallogr. 1981. V. 14. P. 357.
  35. Zlokazov V.B., Chernyshev V. V. // J. Appl. Crystallogr. 1992. V. 25. P. 447.
  36. Zhukov S.G., Chernyshev V. V., Babaev E. V. et al. // Z. Kristallogr. 2001. V. 216. P. 5.
  37. Zlokazov V.B., Chernyshev V. V. // J. Appl. Crystallogr. 1992. V. 25. P. 447.
  38. Andreev S.V., Zverev S. A., Zamilatskov I. A. et al. // Acta Crystallorg. C. 2017. V. 73. P. 47.
  39. Erzina D.R., Zamilatskov I.A, Stanetskaya N. M. et al. // Eur. J. Org. Chem. 2019. P. 1508.
  40. Spek A.L. // Acta Crystallorg. D. 2009. V. 65. P. 148.
  41. Pastukhova Zh. Yu., Levitin V. V., Katsman E. A. et al. // Kinet. Catal. 2021. V. 62. № 5. P. 551.
  42. Groom C.R., Allen F. H. // Angew. Chem. 2014. V. 53. P. 662.
  43. Bordiga S., Bonina F., Damin A. et al. // Phys. Chem. Chem. Phys. 2007. V. 9. № 35. P. 4854.
  44. Taramasso M., Perego G., Notari B. US Pat. № 4410501. 1983.
  45. Flaningen E.M., Bennett J. M., Grose R. W. et al. // Nature. 1978. V. 271. P. 512.
  46. Lane B.S., Burgess K. // Chem. Rev. 2003. V. 103. P. 2457.

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar

Declaração de direitos autorais © Российская академия наук, 2024