Thermochemical properties of trinitromethyl-1,3,5-triazines

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Abstract

The enthalpies of combustion and enthalpies of formation of three trinitromethyl derivatives of 1,3,5-triazine were determined by calorimetric method. The data obtained can be used for calculating the energy capabilities of related compounds by the method of replacing functional groups. As an example, the detonation characteristics of high-energy tris(trinitromethyl)-1,3,5-triazine are calculated.

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About the authors

T. S. Kon’kova

Semenov Institute of Chemical Physics Russian Academy of Sciences

Email: taskon@mail.ru
Russian Federation, Moscow

E. A. Miroshnichenko

Semenov Institute of Chemical Physics Russian Academy of Sciences

Email: taskon@mail.ru
Russian Federation, Moscow

A. V. Shastin

Institute of problems of Chemical Physics Russian Academy of Sciences

Email: taskon@mail.ru
Russian Federation, Chernogolovka

M. N. Makhov

Semenov Institute of Chemical Physics Russian Academy of Sciences

Email: taskon@mail.ru
Russian Federation, Moscow

Yu. N. Matyushin

Semenov Institute of Chemical Physics Russian Academy of Sciences

Email: taskon@mail.ru
Russian Federation, Moscow

B. L. Korsunskiy

Semenov Institute of Chemical Physics Russian Academy of Sciences; Institute of problems of Chemical Physics Russian Academy of Sciences

Author for correspondence.
Email: taskon@mail.ru
Russian Federation, Moscow; Chernogolovka

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2. Fig. 1. Dependence of TV on the content of HMX in a mixture with compound VI.

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3. Fig. 2. Dependence of the MS of explosive compositions on the HMX content. 1 - composition HMX - compound VI, 2 - composition HMX - compound VI - aluminum.

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