In situ synthesis of nano-CeO2 and chitosan composite

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Abstract

Nanosized cerium oxide (CeO2) particles were prepared by co-precipitation method using chitosan as a template, cerium (III) nitrate and cerium (IV) sulfate as starting materials and aqueous ammonia solution as a precipitating agent. XRD data indicate that cerianite with face-centered cubic phase is formed in the reaction systems. The size of the coherent scattering regions is about 3 nm or less. FTIR spectroscopy data indicate the interaction of polymer molecules with the inorganic component. The shift of absorption bands related to N-H bonds for composites with Ce(III) and Ce(IV) compared to chitosan indicates the interaction of amino groups with CeO2 particles. The application of chitosan as a matrix for the synthesis of CeO2 nanoparticles showed that this approach is more economical and easier to produce nanomaterials for various applications.

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About the authors

L. A. Zemskova

Institute of Chemistry, Far Eastern Branch of Russian Academy of Sciences

Author for correspondence.
Email: zemskova@ich.dvo.ru
Russian Federation, Vladivostok, 690022

V. E. Silant’ev

Institute of Chemistry, Far Eastern Branch of Russian Academy of Sciences; Far Eastern Federal University, School of Medicine and Life Sciences

Email: vladimir.silantyev@gmail.com
Russian Federation, Vladivostok, 690022; Vladivostok, 690022

D. Kh. Shlyk

Institute of Chemistry, Far Eastern Branch of Russian Academy of Sciences

Email: zemskova@ich.dvo.ru
Russian Federation, Vladivostok, 690022

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2. Fig. 1. IR Fourier absorption spectra in a wide range and in the range of 500-800 cm–1: HTZ (1, 1a), composites Ce_3_Chit (2, 2a) and Ce_4_Chit (3, 3a).

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3. Fig. 2. Diffractograms of samples of hybrid materials Ce_3_Chit (1), Ce_4_Chit (2).

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4. Fig. 3. SEM images of the composites Ce_3_Chit (a) and Ce_4_Chit (b).

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5. Fig. 4. Results of EMF analysis of Ce_3_Chit (a) Ce_4_Chit (b) composites.

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