Luminescence properties of heterometallic lanthanide complexes based on lithium β-diketonate bearing tert-butyl and acetal group

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Abstract

Nonsymmetrical lithium β-diketonate (LiL) containing tert-butyl and acetal substituents at the dicarbonyl cage has been synthesized for the first time and is structurally characterized (CIF file CCDC no. 2364039 (I)). The reactions of functional lithium β-diketonate with salts of trivalent rare-earth metals in methanol afford heterobinuclear complexes [(LnL3)(LiL)(MeOH)] (Ln = Eu, Gd, Tb). The structures of the complexes are characterized by X-ray diffraction (XRD) (CIF files CCDC nos. 2364040 (II), 2364041 (III), 2364042 (IV)).

About the authors

Yu. O. Edilova

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Email: dnbazhin@gmail.com
Russian Federation, Yekaterinburg

Yu. S. Kudyakova

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Email: dnbazhin@gmail.com
Russian Federation, Yekaterinburg

P. A. Slepukhin

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the first President of Russia B.N. Yeltsin

Email: dnbazhin@gmail.com
Russian Federation, Yekaterinburg; Yekaterinburg

M. S. Valova

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Email: dnbazhin@gmail.com
Russian Federation, Yekaterinburg

V. I. Saloutin

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Email: dnbazhin@gmail.com
Russian Federation, Yekaterinburg

D. N. Bazhin

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the first President of Russia B.N. Yeltsin

Author for correspondence.
Email: dnbazhin@gmail.com
Russian Federation, Yekaterinburg; Yekaterinburg

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