Luminescence properties of heterometallic lanthanide complexes based on lithium β-diketonate bearing tert-butyl and acetal group

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Nonsymmetrical lithium β-diketonate (LiL) containing tert-butyl and acetal substituents at the dicarbonyl cage has been synthesized for the first time and is structurally characterized (CIF file CCDC no. 2364039 (I)). The reactions of functional lithium β-diketonate with salts of trivalent rare-earth metals in methanol afford heterobinuclear complexes [(LnL3)(LiL)(MeOH)] (Ln = Eu, Gd, Tb). The structures of the complexes are characterized by X-ray diffraction (XRD) (CIF files CCDC nos. 2364040 (II), 2364041 (III), 2364042 (IV)).

作者简介

Yu. Edilova

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Email: dnbazhin@gmail.com
俄罗斯联邦, Yekaterinburg

Yu. Kudyakova

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Email: dnbazhin@gmail.com
俄罗斯联邦, Yekaterinburg

P. Slepukhin

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the first President of Russia B.N. Yeltsin

Email: dnbazhin@gmail.com
俄罗斯联邦, Yekaterinburg; Yekaterinburg

M. Valova

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Email: dnbazhin@gmail.com
俄罗斯联邦, Yekaterinburg

V. Saloutin

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Email: dnbazhin@gmail.com
俄罗斯联邦, Yekaterinburg

D. Bazhin

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the first President of Russia B.N. Yeltsin

编辑信件的主要联系方式.
Email: dnbazhin@gmail.com
俄罗斯联邦, Yekaterinburg; Yekaterinburg

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