Monomeric and Polymeric Cyclopentadienyl Dysprosium Complexes Based on the Acenaphthene-1,2-diimine Ligand

D. A. Lukina; Лукина Д. А.; A. A. Skatova; Скатова А. А.; E. A. Kozlova; Козлова Е. А.; I. L. Fedyushkin; Федюшкин И. Л.

doi:10.31857/S0132344X24060024

Monomeric and Polymeric Cyclopentadienyl Dysprosium Complexes Based on the Acenaphthene-1,2-diimine Ligand

作者: Lukina D.A.¹, Skatova A.A.¹, Kozlova E.A.¹, Fedyushkin I.L.¹
隶属关系:
1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
期: 卷 50, 编号 6 (2024)
页面: 363-373
栏目: Articles
URL: https://rjonco.com/0132-344X/article/view/667591
DOI: https://doi.org/10.31857/S0132344X24060024
EDN: https://elibrary.ru/MVSNXD
ID: 667591

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The reaction of [(Dpp-bian)DyI(Dme)₂] (Dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene, Dme is CH₃OCH₂CH₂OCH₃) with Cp*K (Cp* is C₅Me₅) in toluene followed by crystallization from benzene affords crystals of the 1D coordination polymer [(Dpp-bian)DyIKCp*]_n (I)•2.6C₆H₆ (26%) and crystals of the monomeric complex [(Dpp-bian)DyCp*(Dme)] (II)•1.5C₆H₆ (12%). The same reaction in 1,2-dimethoxyethane followed by crystallization from benzene makes it possible to isolate only complex II•1.5C₆H₆ in a yield of 48%. The synthesized compounds are characterized by IR and UV spectroscopy and elemental and thermogravimetric analyses. Their molecular structures are determined by XRD (CIF files CCDC nos. 2298407 (I) and 2298408 (II)).

关键词

dysprosium, cyclopentadienyl, 1,2-bis(arylimino)acenaphthene, coordination polymer, redox-active ligand

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作者简介

D. Lukina

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: igorfed@iomc.ras.ru
俄罗斯联邦, Nizhny Novgorod

A. Skatova

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: igorfed@iomc.ras.ru
俄罗斯联邦, Nizhny Novgorod

E. Kozlova

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: igorfed@iomc.ras.ru
俄罗斯联邦, Nizhny Novgorod

I. Fedyushkin

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: igorfed@iomc.ras.ru
俄罗斯联邦, Nizhny Novgorod

参考

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2. Fig. 1. Electronic absorption spectra of complexes I(1) and II(2) in benzene.

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3. Fig. 2. Thermogravimetric analysis of complexes I (a) and II (b): TG (1), DTG (2).

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4. Fig. 3. Fragment of the molecular structure of 1D-coordination polymer I. Hydrogen atoms are not shown.

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5. Fig. 4. Fragment of the crystal packing of complex I. Crystallographic projections along the a (a) axis and along the c (b) axis are presented. Hydrogen atoms and solvent molecules are not shown.